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IMPORTANT NOTE: For bath and body products, use with extreme caution any fragrance oil containing, cinnamon, cherry, spice, almond, lime, even in small amounts. These fragrances are unusually concentrated and sometimes known to be irritable to some skin types. Only a few fragrances fit into this category and these ingredients would be listed in either the title or the description.
MATERIAL SAFETY DATA SHEET EU-COMPLIANT SAFETY DATA SHEET
In accordance with REACH Regulation EC No. 1907/2006 & REACH Regulation EC No. 1272/2008
Arts-set 34 Avenue des Champs-Elysées 75008 Paris - France
Phone: 33-0988773206 http://www.ars-set.fr
Email: contact@arts-set.fr
MATERIAL SAFETY DATA SHEET
1.1 Product Identifier | Key Note: Pink Peppercorn - INCI: Fragrance |
Harmonization Codes HS: | 330129 Other Essential Oils 330290 Other Mixtures of Odoriferous Substances 330300 Perfumes and Toilet Waters 330730 Perfumed Bath Salts and Other Bath Preparations 330741 Agarbatti and Other Odoriferous Preparations Which Operate By Burning 330749 Other Preparations for Perfuming or Deodorizing Rooms 330790 Depilatories, Other Perfumery, Cosmetic or Toilet Preparations |
1.2 Product Uses and Uses Advised Against: |
Use in Fragrance Products. |
1.3 Manufacturer/Supplier: |
Arts-set Further information obtainable from: Email: contact@arts-set.fr |
1.4 Emergency Telephone Number: | In case of emergency phone 33-0988773206 outside office hours, your local Emergency Room. IF SWALLOWED CALL YOUR POISON CONTROL CENTER |
SECTION 2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture in accordance with paragraph (d) of §1910.1200; | This mixture has not been tested as a whole. The effects, listed below, are based on evaluation of individual components in accordance with the provisions of the regulations(s) noted below and account for all concentrations, SOS, ULTRA and EXTREME and related properties of each concentration. | |
Classification under (EC) Regulation No. 1272/2008 |
Flammable Liquids, Category 3 |
H226: Flammable liquid and vapor. |
Pictograms: | ||
Classification under (EC) Directive 1999/45/EC | ||
Irritating to skin and eyes. May cause sensitization. See Section 15. | ||
Hazard Symbols: Risk Phrases: |
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2.2 Label Elements and Information Concerning Particular Hazards For Human And Environment: | See Section 15. | |
2.3 Classification system: | Directives 67/548/EEC or 1999/45/EC. | |
2.4 Other Hazards: | None. | |
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Chemical Characterization Description: A mixture of fragrance chemicals and/or essentials oils and isolates. 3.2 Dangerous Components:
Substances with Community workplace exposure limits, not listed above: Not Applicable The specific chemical identity and/or exact percentrage (concentration) of composition has been withheld as a trade secret is required. |
SECTION 4. FIRST AID MEASURES
4.1 Description Of First Aid Measures | |
Inhalation: | This material does not present a hazard if inhaled. Remove individual to fresh air and keep at rest in a position comfortable for breathing; as a precautionary measure. Consult a doctor in case of complaints. |
Skin Contact: | Immediately wash with soap and water and rinse thoroughly. Remove soiled clothing. Then consult a doctor. |
Eye Contact: |
Immediately rinse opened eye for several minutes under running water. Rinse cautiously for several minutes, retracting eyelids often. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Remove contact lenses, if present and easy to do. Continue rinsing. Then consult a doctor. |
Swallowing: | Rinse mouth, then make victim drink plenty of water; avoid vomiting (risk of perforation!). Immediately call a doctor. Do not attempt to neutralize. |
4.2 Most Important Symptoms And Effects (Acute or Delayed) | |
Causes skin irritation. May cause an allergic reaction. Causes serious eye damage. |
|
4.3 Indication Of Any Immediate Medical Attention And Special Treatment Needed | |
None expected, see Section 4.1 for further information. |
SECTION 5. FIRE FIGHTING MEASURES
5.1 Suitable Extinguishing Agents: | Combustible at elevated termperatures. Use alcohol resistant foam, carbon dioxide, dry chemical, or water spray when fighting first - CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Use fire-extinguishing methods suitable to surrounding conditions. Water or foam may cause frothing if liquid is burning but it still may be a useful extinguishing agent if carefully applied to the fire. Do not direct a water stream directly into the hot burning liquid. |
5.2 Special Hazards Caused By The Substance, Its Products Of Combustion Or Resulting Gases: |
Material may be ignited if preheated to termperatures above the flash point in the presence of a source of ignition. In case of fire, the following can be released: |
5.3 Protective Methods And Equipment For Firefighting: | Do not enter fire area without proper protection including self-contained breathing apparatus, repiratory protective equipment and full protective suit/equipment. Fight fire from a safe distance and a protected location due to the potential of hazardous vapors and decomposition products. |
5.4 Additional Information: | N/A |
SECTION 6. ACCIDENTAL RELEASE MEASURES
6.1 Person-Related Safety Precautions: | Isolate spillage and clean up immediately. Avoid inhalation. Avoid contact with skin and eyes. Refer to Section 7 & Section 8 for protective measures when handling the spillage. |
6.2 Measures For Environmental Protection: | Do not allow liquid to enter drains, surface and ground water, and soil. |
6.3 Measures For Cleaning/Collecting: |
Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose of according to local regulations and according to Section 13. Rinse off area with water. |
6.4 Reference To Other Sections: | Also refer to Section 8 and Section 13. |
SECTION 7. HANDLING AND STORAGE
7.1 Precautions For Safe Handling: |
Observe the general safety regulations when handling chemicals. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation. Avoid inhalation. Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Do not eat, drink or smoke when using this product. Avoid contact with the eyes, skin and mucous membranes. |
7.2 Storage: | Store in original container at or below 25°C. Store in a well ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion -proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. |
7.3 Requirements To Be Met By Storerooms And Receptacles: | Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. |
7.4 Specific End Use(s): | Use in accordance with good manufacturing and industrial hygiene practices. |
SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
8.1 Control Parameters | |
Ingredients With Limit Values That Require Monitoring In The Workplace: | None. |
Additional Information: | N/A |
8.2 Exposure Controls | |
Personal Protective Equipment: |
Wear protective gloves/eye protection/face protection. |
Respiratory Protection: | Under normal conditions of use and where adequate ventilation is available to prevent build up of excessive vapour, this material should not require special engineering controls. However, in conditions of high or prolonged use, or high temperature or other conditions which increase exposure, the following engineering controls can be used to minimize exposure to personnel: a) Increase ventilation of the area with local exhaust ventilation. b) Personnel can use an approved, appropriately fitted respirator with organic vapour cartridge or canisters and particulate filters. c) Use closed systems for transferring and processing this material. Also refer to Sections 2 and Section 7. |
General Protective And Hygienic Measures: |
Follow Good Laboratory and Manufacturing Practices (GLP/GMP). Wash hands before breaks and at the end of work. |
Protection Of Hands: |
Disposable gloves |
Eye Protection: | Safety glasses |
Body Protection: | Lab Coat |
Respiratory Protection: | NIOSH-approved organic vapor respiration or equivalent. |
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
General Information
Appearance/Form: | Liquid |
Color: | Clear to Brown |
Odor: | To match standard. Scent character: A Mobile Liquid with odor. Why Pink Peppercorn is a Key Note: Any and all pepper notes should be present in a true fragrance library. Not only is it spicy and sensitive, it is also mysterious and dark. It brings a classy, yet underground finish to any perfume. Important Free Sample Policy Note: Due to the high cost of raw materials associated with this rare and high end fragrance note, we are unable to provide free samples. If requested in a Free Sampler Pack during checkout, we will replace with an alternate substitution. We are sorry for the inconvenience and thank you for your understanding. |
Change In Condition | |
Melting Point/Melting Range: | Not determined |
Boiling Point/Boiling Range: | Not determined |
Flashpoint (°F): | SOS: 230°F ULTRA: 198°F EXTREME: 167. If not listed, please call for flashpoint(s). |
Self-Igniting: | Will not self-ignite. |
Danger Of Explosion: | Does not present an explosion hazard. |
Vapor Pressure: | >0.0009 mm Hg @ 20°C |
Density at 25°C: | 0.975-1.2 g/cc |
Solubility In/Miscibility With Water: | No |
pH-value At 20°C: | Not determined |
Octonol/Water Partition Coefficient: | 4.1 - 9.3 at 25°C 4.7 |
Volatiles, % By Weight: | 5.1-6.7 |
Bulk Density: | 321.8 - 410.1 |
Other Information: | None. |
SECTION 10. STABILITY AND REACTIVITY
Reactivity: | Presents no significant reactivity hazard, by itself, or in contact with water. |
Stability: | Stable when stored in accordance with the recommended storage conditions. |
Materials To Be Avoided: |
Avoid contact with strong acids, alkalis or oxidising agents. |
Hazardous Reactions: | No dangerous reactions known. Not expected under normal conditions of use. |
Conditions To Avoid: | Avoid extreme heat. |
Hazardous Decomposition Products: | CO2, CO |
SECTION 11. TOXICOLOGICAL INFORMATION
11.1 Information On Toxicological Effects This mixture has not been tested as a whole for health effects. The health effects have been calculated using the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC, in accordance with Regulation (EC) No 1907/2006 (REACH). In addition, toxicity information for the mixture, if available, is provided below in accordance with methods given in Regulation (EC) No 1272/2008. |
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Acute Toxicity (LD/LC50) Values Relevant For Classification:: |
Calculated LD50: 1.2 - 1.7 g/kg |
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Assumed Toxicity Value (LD50 or ATE) for Acute Oral Toxicity: | 3471.45 - 4209.26 | ||||||||||||||||||||||||||||
Assumed Toxicity Value (LD50 or ATE) for Acute Dermal Toxicity: | 9398.1 - 14159.34 | ||||||||||||||||||||||||||||
Assumed Toxicity Value (LC50 or ATE) for Acute Inhalation Toxicity: | Not available | ||||||||||||||||||||||||||||
Inhalation Route: | Not available | ||||||||||||||||||||||||||||
Primary Effects: |
After skin contact: Irritation. Chronic exposure may cause damage to skin and kidneys. |
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Information about hazardous ingredients in the mixture: | |||||||||||||||||||||||||||||
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SECTION 12. ECOLOGICAL INFORMATION
12.1 Toxicity: | Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. See Section 15. |
12.2 Persistence And Degradability: | Not determined. |
12.3 Bioaccumulative Potential: | Not determined. |
12.4 Mobility In Soil: | Not determined. |
12.5 Results of PBT and vPvB Assessment: | This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII. |
12.6 Other Adverse Effects: | Not determined. |
SECTION 13. DISPOSAL CONSIDERATIONS
13.1 Product: |
Chemical residues and remains should be routinely handled as special waste. This must be disposed of incompliance with anti-pollution and other laws of the country concerned. To ensure compliance we recommend that you contact the relevant (local) authorities and/or an approved waste-disposal company for information. |
13.2 European Waste Catalogue: | 07 07 04 other organic solvents, washing liquids and mother liquors |
13.3 Packaging: | Disposal must be made in accordance with local waste management regulations. Contaminated packaging must be disposed of in the same manner as the product. Non-contaminated packaging materials may be recycled. Contact your local service providers for further information. |
13.4 Disposal Methods: | DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State, Provincial, and local laws and regulations. Regulations vary in different locations. Waste characterizations and compliance with applicable laws are the sole responsibility of the waste generator. As your suuplier, we have no control over the management practices or manufacturing processes of parties handling or using this material. The information presented here pertains only to the product when used as intended, according to this Safety Date Sheet. For unused and uncontaminated product, the preferred options include sending to a licensed and permitted incinerator or other thermal destruction device. Various federal, state or provincial agencies may have specific regulations concerning the transportation, handling, storage, use or disosal of this product which may not be covered in the Safety Data Sheet. The user shall have to review these regulations to ensure full compliance with all applicable regulations. |
SECTION 14. TRANSPORTATION INFORMATION
14.1 UN number: |
UN3082 |
14.2 UN Proper Shipping Name: | ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. |
Flashpoint (°F): | SOS: 230°F ULTRA: 198°F EXTREME: 167°F. If not listed, please call for flashpoint(s). |
14.3 Transport Hazard Class(es): | 9: 100-140°F (Flammable), 3A: 140-200°F (Combustible). 3B: >200°F (Not Regulated) |
Road/Rail (CDGRR ADR, RID): Not Restricted |
|
Sub Risk: | - |
14.4. Packing Group: | III |
14.5 Environmental Hazards: | This is an environmentally hazardous substance. |
14.6 Special precautions for user: | None additional |
14.7 Transport In Bulk According To Annex II Of MARPOL73/78 And The IBC Code: | Not applicable |
SECTION 15. REGULATORY INFORMATION
15.1 TSCA Status & Safety, Health And Environmental Regulations/Legislation Specific For The Substance Or Mixture: |
All components in this product are on the TSCA Inventory. None Additional.
|
15.2 Chemical Safety Assessment | A Chemical Safety Assessment has not been carried out for this product. |
15.3 Labeling According To EU Guidelines: | Code letter and hazard designation of product: Xi, Irritant Xn, Harmful N, Dangerous for the environment |
15.4 Hazard-Determining Components Of Labeling: | See Section 3 |
15.5 Risk Phrases(R): |
10 Flammable. |
15.6 Safety Phrases(S): |
02 Keep out of reach of children. |
15.7 Class And Category Of Danger: |
Flammable Liquid: Hazard Category 3 |
15.8 Signal Word: | Warning, Danger |
15. 9 Hazard Phrases(H): | 226 Flammable liquid and vapour. 303 May be harmful if swallowed. 304 May be fatal if swallowed and enters airways. 313 Maybe be harmful in contact with skin. 315 Causes skin irritation. 317 May cause an allergic skin reaction. 318 Causes serious eye damage. 333 May be harmful if inhaled. 410 Very toxic to aquatic life with long lasting effects. 412 Harmful to aquatic life with long lasting effects. |
Supplemental Information: | No Animal testing. No animal products or byproducts are used in this fragrance. May produce an allergic reaction. |
Precautionary Statements(P): | 210 Keep away from heat, sparks, open flames and hot surfaces. - No smoking. 233 Keep container tightly closed. 240 Ground/bond container and receiving equipment. 241 Use explosion-proof electrical ventilating and lighting equipment. 242 Use only non-sparking tools. 243 Take precautionary measures against static discharge. 261 Do not breathe vapour or dust. 264 Wash hands and other contacted skin thoroughly after handling. 272 Contaminated work clothing should not be allowed out of the workplace. 273 Avoid release to the environment. 280 Wear protective gloves/eye protection/face protection. 301/330/331 IF SWALLOWED: Rinse mouth. Do not induce vomiting. 302/352 IF ON SKIN: Wash with plenty of soap and water. 302/303/361/353 IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. 304/340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. 305/351/338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contactlenses, if present and easy to do. Continue rinsing. 310 Immediately call a POISON CENTER or doctor/physician. 333/313 If skin irritation or rash occurs: Get medical advice/attention. 362 Take off contaminated clothing and wash before reuse. 363 Wash contaminated clothing before reuse. 370/378 In case of fire: Use carbon dioxide, dry chemical, foam for extinction. 391 Collect Spillage. 403/235 Store in a well-ventilated place. Keep cool. 405 Store locked up. 501 Dispose of contents/container to approved disposal site, in accordance with local regulations. |
Pictograms: | |
Other Hazards: | None |
Concentration % Limits | EH A1= 90.20% EH C1=90.20% EH C2=9.02% EH C3=0.92% EH C4=10% SCI 1A=90.02% SCI 2=47.50% SS 1=4.74% |
Total Fractional Values | EH A1= 1.16 EH C1=1.16 EH C2=11.52 EH C3=115.47 EH C4=10.90 SCI 1A=4.93 SCI 2=2.60 SS 1=26.00 |
Key To Revisions: | Not applicable. |
Key To Abbreviations: |
AH 1 Aspiration - Hazard Category 1 |
SECTION 16. OTHER INFORMATION
This information is based on use of product neat, and not use of product in project bases, but on use as a fragrance concentrate. For detailed information on the categories below, please refer to the IFRA QRA Information Booklet.
Table 1: SAF and Product Type Consumer Exposure Levels that Drive the IFRA QRA Category
IFRA QRA Category
|
SAF
|
Category Consumer Exposure*
mg/cm2/day |
Product Type That Drives the Category Consumber Exposure Level
|
Minimum Pragmatic Level
|
Category 1 (C1)
|
300
|
11.7
|
Lip Products
|
Not Necessary
Acceptable Exposure Level derived from IFRA QRA |
Category 2 (C2)
|
300
|
9.1
|
Deodorants/Antiperspirants
|
Not Necessary
Acceptable Exposure Level derived from IFRA QRA |
Category 3 (C3)
|
300
|
2.2
|
Hydroalcoholics for Shaved Skin
|
Not Necessary
Acceptable Exposure Level derived from IFRA QRA |
Category 4 (C4)
|
100
|
2.2
|
Hydroalcoholics for Unshaved Skin
|
Not Necessary
Acceptable Exposure Level derived from IFRA QRA |
Category 5 (C5)
|
100
|
4.2
|
Hand Cream
|
Not Necessary
Acceptable Exposure Level derived from IFRA QRA |
Category 6 (C6)
|
100
|
1.4
|
Mouthwash
|
Not Necessary
Acceptable Exposure Level derived from IFRA QRA |
Category 7 (C7)
|
300
|
4.4
|
Intimate Wipes
|
Not Necessary
Acceptable Exposure Level derived from IFRA QRA |
Category 8 (C8)
|
100
|
1.0
|
Hair Styling Aids
|
2% The maximum concentration will not exceed 2% and may be lower if determined by the IFRA QRA
|
Category 9 (C9)
|
100
|
0.2
|
Rinse-off Hair Conditioners
|
5% The maximum concentration will not exceed 5% and may be lower if determined by the IFRA QRA
|
Category 10 (C10)
|
100
|
0.1
|
Hard Surface Cleaners
|
2.5% The maximum concentration will not exceed 2.5% and may be lower if determined by the IFRA QRA
|
Category 11 (C11)
|
10
|
0.00033
|
Candles
|
Due to the expected negligible skin exposure from such products the risk of induction of dermal sensitization through the normal formulation and use of such products is considered to be negligible. As such, the concentration of fragrance ingredient is not restricted in the finished product.
|
* The Category Consumer Exposure Level (mg/cm2/day) is driven by the product type in that category with the combined highest consumer exposure level and highest Sensitization Assessment Factor (SAF). In order to identify the product type consumer exposure that drives the category consumer exposure, please refer to the Technical Dossier, Table 9 in the IFRA QRA Information Booklet.
Table 2: Components-Allergens***
Level | CAS Nr | EC Nr |
Substance |
R Phrase: Classification for |
Classification for
(CLP) 1272/2008 |
LD50/ATE Oral |
LD50/ATE |
LC50/ATE
Inhalation |
LC50 Route |
0-0.5% | 122-40-7 | 204-541-5 |
alpha-Amyl Cinnamic Aldehyde | Xi; R21/41 R38 R43 | SS 1B EH C2; H317 H411 | 3730 | Not determined | Not determined | Not determined |
C1=0.02% C2=0.02% C3=0.05% C4=0.05% C5=0.05% C6=0.4% C7=.04% C8=.05% C9=.05% C10=.05% C11=Not Restricted (type floral, medium strength described as sweet, floral, oily, fruity, herbal, jasmin, tropical, green, powdery, waxy) |
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0-2.5% | 100-51-6 | 202-859-9 | Benzyl Alcohol | Xn, R20/R22 | ATO 4 EDI 2 ATI 4; H302 H319 H332 | 1040 | 2000 | 1000 | Not determined |
C1=0.2% C2=0.2% C3=0.9% C4=2.7% C5=1.4% C6=4.3% C7=0.4% C8=.2.0% C9=5.0% C10=2.5% C11=Not Restricted (type floral, medium strength described as floral, rose, balsamic, sweet, fruity, chemical) |
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0-0.4% | 104-54-1 | 203-212-3 |
Cinnamic Alcohol | None | SCI 2 EDI 2; H315 H319 | 2000 | >5000 | Not determined | Not determined |
C1=0.09% C2=0.1% C3=0.4% C4=0.4% C5=0.4% C6=2.2% C7=0.2% C8=.0.2% C9=0.4% C10=0.4% C11=Not Restricted (type balsamic, medium strength described as sweet, balsam, hyacinth, spicy, green, powdery, cinnamic, floral, yeasty) |
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0-5% | 5392-40-5 | 226-394-6 |
Citral | Xi; R38 R43 | SCI 2 SS 1B EDI 2; H315 H317 H319 | 4960 | 2250 | Not determined | Not determined |
C1=0.04% C2=0.05% C3=0.2% C4=0.6% C5=0.3% C6=1% C7=0.1% C8=.1.4% C9=5% C10=2.5% C11=Not Restricted (type citrus, medium strength described as sharp, lemon, sweet, tangy, green, citrus, juicy, lime, woody, herbal) |
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0-.4.3% | 97-53-0 | 202-589-1 |
Eugenol | Xn Xi; R36 R43 | SS 1B EDI 2; H317 H319 | 1930 | 5000 | 2580 | Not determined |
C1=0.2% C2=0.2% C3=0.5% C4=0.5% C5=0.5% C6=4.3% C7=0.4% C8=.0.5% C9=0.5% C10=0.5% C11=Not Restricted (type spicy, medium strength described as sweet, spicy, close, woody, allspice) |
||||||||
0-3.6% | 107-75-5 | 203-518-7 |
7-Hydroxy-Citronellal | Xi; R36, R43 | SS 1B EDI 2; H317 H319 | 5000 | 2000 | Not determined | Not determined |
C1=0.1% C2=0.2% C3=0.8% C4=1.0% C5=1.0% C6=3.6% C7=0.4% C8=1% C9=1% C10=1% C11=Not Restricted (type floral, medium strength described as floral, lily, sweet, green, waxy, tropical, melon) |
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0-0.2% | 97-54-1 | 202-590-7 |
Isoeugenol | Xi; R21/41 R38 R43 | SS 1B EDI 2; H317 H319 | 1560 | Not Determined | Not determined | Not determined |
C1=0.01% C2=0.01% C3=0.02% C4=0.02% C5=0.02% C6=0.2% C7=0.02% C8=0.02% C9=0.02% C10=0,02% C11=Not Restricted (type spicy, medium strength described as sweet, spicy, clove, woody, carnation, floral) |
||||||||
0-3.5% | 101-85-9 | 202-982-8 |
alpha-Amyl Cinnamic Alcohol | Xi; R21/41 R38 R43 | SS 1B EDI 2; H317 H319 | 4000 | >5000 | Not determined | Not determined |
C1=0.02% C2=0.03% C3=0.11% C4=0.32% C5=0.17% C6=0.51% C7=0.05% C8=0.07% C9=3.5% C10=2.5% C11=Not Restricted (type spicy, medium strength, floral, jasmine, rosy, waxy, sweet spicy, woody, cinnamon nuance) |
||||||||
0-12.8% |
118-58-1 | |
Benzyl Salicylate |
Xi N; R43 R51/53 |
SS 1B EDI 2 ETO C3; H317 H319 H412 |
2227 |
Not determined |
Not determined | Not determined |
C1=0.5% C2=0.7% C3=2.7% C4=8% C5=4.2% C6=12.8% C7=1.3% C8=2% C9=5% C10=2.5% C11=Not Restricted (type balsamic, low strength, described as balsam, clean, herbal, oily, sweet) |
||||||||
0-.4% | 104-55-2 | 203-213-9 |
Cinnamic Aldehyde | None | ATD 4 SS 1 SCI 2 EDI 2; H312 H315 H317 H319 | 2220 | .59 | .Not determined | Not determined |
C1=0.02% C2=0.02% C3=0.05% C4=0.05% C5=0.05% C6=0.4% C7=0.04% C8=0.05% C9=0.05% C10=0.05% C11=Not Restricted (type spicy, high strength, described as sweet, spice, cinnamon, red hots, warm) |
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0-5% | 91-64-5 | 202-086-7 |
Coumarin | Xn N; R20/21/22 R43 R51/53 | ATO 4 SS 1 ETO C3; H302 H317 H412 | 293 | 242 | Not determined | Not determined |
C1=0.1% C2=0.13% C3=0.5% C4=1.6% C5=0.8% C6=2.5% C7=0.3% C8=2% C9=5% C10=2.5% C11=Not Restricted (type tonka, medium strength, described as sweet, hay, tonka, new mown hay) |
||||||||
0-8.6% | 106-24-1 | 203-377-1 |
Geraniol | Xi; R38 R41 R43 | SCI 2 SS 1 EDI 1; H315 H317 H318 | 3600 | 5000 | Not determined | Not determined |
C1=0.3.% C2=0.4% C3=1.8% C4=5.3% C5=2.8% C6=8.6% C7=0.9% C8=2% C9=5% C10=2.5% C11=Not Restricted (type floral, medium strength, described as sweet, floral, fruity, rose, waxy, peach, citrus) |
||||||||
0-0.2% | 31906-04-4 | 250-863-4 |
HMPCC (Lyrall) | Xi; R43 | SS 1B; H317 | 3250 | 11300 | Not determined | Not determined |
C1=0.02.% C2=0.02% C3=0.2% C4=0.2% C5=0.2% C6=0.2% C7=0.02% C8=0.2% C9=0.2% C10=0.2% C11=Not Restricted (type floral, medium strength, described as floral, muguet, cyclamen, rhubarb, woody) |
||||||||
0-5% | 105-13-5 | 203-273-6 |
(4-Methoxybenzyl) Anysil Alcohol | None | SCI 1B EDI 1; H315 H318 | 1340 | 3000 | Not determined | Not determined |
C1=0.04.% C2=0.1% C3=0.2% C4=0.7% C5=0.4% C6=1.1% C7=0.1% C8=1.5% C9=5% C10=2.5% C11=Not Restricted (type powdery, medium strength, described as sweet, powdery, hawthorn, lilac, rose, floral, hyacinth, creamy, balsamic, coumarin, cherry, vanilla, licorice, anise) |
||||||||
0-5% | 103-41-3 | 203-109-3 |
Benzyl Cinnamate | None | SCI 1B EDI 1; H315 H318 | 5530 | >3000 | Not determined | Not determined |
C1=0.1.% C2=0.2% C3=0.7% C4=2.1% C5=1.1% C6=3.4% C7=0.4% C8=2% C9=5% C10=2.5% C11=Not Restricted (type balsamic low strength, described as sweet, balsamic, floral, fruity, cherry, spicy, powdery) |
||||||||
0-5% | 4602-84-0 | 225-004-1 |
Farnesol | None | EDI 2 EH A1 ETO C1; H319 H400 H410 | 6000 | >5000 | Not determined | Not determined |
C1=0.08.% C2=0.11% C3=0.4% C4=1.2% C5=0.6% C6=2% C7=0.2% C8=2% C9=5% C10=2.5% C11=Not Restricted (type floral low strength, described as mild, fresh, sweet, linden, floral, angelica) |
||||||||
0-3% | 80-54-6 | 201-289-8 |
2-(4-tert-Butylbenzyl) Propionaldehyde (Lilyall/BMHCA) | Xn Xi N; R22 R38 R43 R51/53 R61 R62 | ATO 4 SS 1B SCI 2 REP 2 ETO C2; H302 H315 H317 H361 H411 | 1390 | >5000 | Not determined | Not determined |
C1=0.1.% C2=0.2% C3=0.6% C4=1.9% C5=1% C6=3% C7=0.3% C8=2% C9=2.5% C10=2.5% C11=Not Restricted (type floral medium strength, described as floral, muguet, watery, green, powdery, cumin) |
||||||||
0-12% | 78-70-6 | 201-134-4 |
Linalool | Xi; R38 | SCI 2 EDI 2; H315 H319 | 2200 | 5610 | Not determined | Not determined |
C1=1% C2=2% C3=2% C4=1% C5=5% C6=2% C7=1% C8=2% C9=12% C10=5% C11=Not Restricted (type floral medium strength, described as citrus, floral, sweet, bois de rose, woody, green, blueberry) |
||||||||
0-42.8% | 120-51-4 | 204-402-9 |
Benzyl Benzoate | Xn N; R22 R51/53 | ATO 4 EH C1 ETO C3; H302 H400 H411 H412 | 1700 | 4000 | Not determined | Not determined |
C1=1.7% C2=2.2% C3=8.9% C4=26.7% C5=14% C6=42.8% C7=4.5% C8=2% C9=5% C10=2.5% C11=Not Restricted (type balsamic low strength, described as faint, sweet, balsam, oily, herbal, fruity) |
||||||||
0-13.3% | 106-22-9 | 203-375-0 |
Citronellol | Xi N; R36/38 R43 R51/53 | SCI 2 EDI 2 SS 1B; H315 H317 H319 | 3450 | 2650 | Not determined | Not determined |
C1=0.8% C2=1.1% C3=4.4% C4=13.3% C5=7% C6=21.4% C7=2.2% C8=2% C9=5% C10=2.5% C11=Not Restricted (type citrus, medium strength described as sweet, green, citrus, rose, woody, herbal) |
||||||||
0-17.1% | 101-86-0 | 202-983-3 | alpha-Hexyl Cinnamic Aldehyde | Xi N; R38 R43 R50/53 | SS 1; H317 | 3100 | Not determined | Not determined | Not determined |
C1=0.7% C2=0.9% C3=3.6% C4=10.7% C5=5.6% C6=17.1% C7=1.8% C8=2% C9=5% C10=2.5% C11=Not Restricted (type floral, medium strength described as fresh, floral, green, jasmin, herbal, waxy, citrus, fruity) |
||||||||
0-20% | 5989-27-5 | 227-813-5 |
dextro-Limonene (R)-p-Mentha-1,8-diene |
Xi N; R10 R38 R43 R50/53 R65 | FL 3 AH 1 SCI 2 SS 1B EH A1 ETO C1; H226 H304 H315 H317 H400 H410 | >5000 | >5000 | Not determined | Not determined |
C1=1.4% C2=1.9% C3=4.6% C4=12.7% C5=6% C6=20% C7=2.8% C8=3% C9=7% C10=3.5% C11=Not Restricted (type citrus, medium strength described as citrus, orange fresh sweet) |
||||||||
0-0.08% | 111-12-6 | 203-836-6 |
Methyl Heptine Carbonite | Xi; R21/41 R38 R43 | SS 1B EDI 2; H317 H319 | 1530 | 3300 | Not determined | Not determined |
C1=0.003% C2=0.004% C3=0.01% C4=0.01% C5=0.01% C6=0.08% C7=0.008% C8=0.01% C9=0.01% C10=0.01% C11=Not Restricted (type green, high strength described as green, leafy, waxy, violet, cucumber) |
||||||||
0-50.7% | 127-51-5 | 204-846-3 |
alpha-Isomethyl Ionone | Xi N; R36/38 R51/53 | SCI 2 EDI 2 ETO C2; H315 H319 H411 | >5000 | >5000 | Not determined | Not determined |
C1=2% C2=2.6% C3=10.6% C4=31.7% C5=16.7% C6=50.7% C7=5.3% C8=2% C9=5% C10=2.5% C11=Not Restricted (type floral, medium strength described as woody, violet, floral) |
||||||||
0-0.5% | 90028-67-4 | 289-860-8 |
Treemoss Extract | Xi; R21/41 R38 R43 | SS 1B EDI 2; H317 H319 | 4330 | >5000 | Not determined | Not determined |
C1=-0.02% C2=0.03% C3=0.1% C4=0.1% C5=0.1% C6=0.5% C7=0.1% C8=0.1% C9=0.1% C10=0.1% C11=Not Restricted (type woody, medium strength described as woody, tar) |
||||||||
0-0.5% | 90028-68-5 | 289-861-3 |
Oakmoss Extract | Xi; R21/41 R38 R43 | SS 1B EDI 2; H317 H319 | 4330 | >5000 | Not determined | Not determined |
C1=-0.02% C2=0.03% C3=0.1% C4=0.1% C5=0.1% C6=0.5% C7=0.1% C8=0.1% C9=0.1% C10=0.1% C11=Not Restricted (type mossy, medium strength described as oakmoss) |
*** These ingredients appear on the list of substances in Annex III of Regulation (EC) No. 1223/2009 on cosmetic products and Annex III Part 1 of Council Directive 76/768/ECC with amendments of Cosmetic Directive 2008/42/EC of 3 April 2008 as referred to by Regulation (EC) No. 648/2004 on detergents.
Table 3: Components-Common
Level | CAS Nr | EC Nr |
Substance |
R Phrase: Classification for |
Classification for
(CLP) 1272/2008 |
LD50/ATE Oral |
LD50/ATE |
LC50/ATE
Inhalation |
LC50 Route |
0-25.7% | 2050-08-0 | 218-080-2 |
Hexyl (Amyl) Salicylate | Xi Xn N; R22 R38 R43 R50/53 R51/53 | H315 H317 H410 |
2000 |
Not determined |
Not determined | Not determined |
C1=-1% C2=1.3% C3=5.3% C4=16% C5=8.4% C6=25.7% C7=2.7% C8=2% C9=5% C10=2.5% C11=Not Restricted (type floral, medium strength described as herbal, floral, clover, azalea, sweet, chocolate) |
||||||||
0-10% | 107-31-3 | 203-481-7 | Methyl Formate | F+ Xn Xi; R12 R20/22 R36/37 | FL 1 ATO 4 ATD 3 EDI 2 EDI 2A SCI 2 ATI 4 STOT SE3 STOT SE1; H224 H301 H302 H311 H319 H331 H332 H335 H370 | 1500 | 4000 | Not determined | Not determined |
C1=-0.03% C2=0.04% C3=0.1% C4=0.1% C5=0.1% C6=0.8% C7=0.08% C8=0.1% C9=0.1% C10=0.1% C11=Not Restricted (type fruity, medium strength described as fruity, plum) |
||||||||
0-5% | 79-20-9 | 201-185-2 | Methyl Acetate | F Xi Xn T; R11 R20/21/22 R36 R39/23/24/25 R66 R67 | FL 2 ATO 4 ATD 4 EDI 2 STOT SE3 STOT SE1; H225 H302 H312 H319 H332 H336 H370 | 5000 | 5000 | Not determined | Not determined |
C1=-0.07% C2=0.08% C3=0.35% C4=1.04% C5=0.55% C6=1.67% C7=0.17% C8=2% C9=5% C10=2.5% C11=Not Restricted (type ethereal, medium strength described as ether, sweet, fruity, solvent-like, green, fresh, rum, cognac, whiskey) |
||||||||
0-2% | 623-42-7 | 210-792-1 | Methyl Butyrate (Methyl Butanoate) |
F Xn Xi; R11 R20 R36/37/38 | FL 2 | 5000 | 3560 | 18000 | Not determined |
(type fruity, medium strength described as fruity, apple, sweet, pineapple, banana) | ||||||||
0-10% | 141-78-6 | 205-500-4 | Ethyl Ethanoate (Ethyl Acetate) | F Xi Xn T; R10 R11 R20/21/22 R36 R39/23/24/25 R66 R67 R68/20/21/22 | FL 2 EDI 2 STOT SE3; H225 H319 H336 | 5620 | 5000 | 200000 | Not determined |
(type ethereal, high strength described as ethereal, fruity, sweet, weedy, green, rum-like, cherry) | ||||||||
0-8% | 105-54-4 | 203-306-4 | Ethyl Butyrate (Ethyl Butanoate) |
Xi; R10 R36/37/38 | FL 3 SCI 2 EDI 2A STOT SE3; H226 H315 H319 H335 H373 | 13000 | 2000 | Not determined | Not determined |
(type fruity, high strength described as fruity, juicy, sweet, pineapply, cognac, tutti frutti, apple ethereal) | ||||||||
0-25% | 123-92-2 | 204-662-3 | Isoamyl Acetate (Isopentyl Acetate) | Xi; R10 R66 | FL 3 STOT SE3 EH A1; H226 H335 H402 | 16600 | 5000 | Not determined | Not determined |
(type fruity, high strength described as sweet, banana, fruity, estry) | ||||||||
0-8% | 540-18-1 | 208-739-2 | Amyl Butyrate Pentyl Butanoate |
Xi; R36/37/38 | None | 12200 | Not Determined | Not determined | Not determined |
(type fruity, medium strength described as sweet, banana, fruity, cherry, pineapple, tropical) | ||||||||
0-3% | 2173-56-0 | 218-528-7 | Amyl Valerate (Pentyl Pentanoate) | None | None | 35420 | Not determined | Not determined | Not determined |
(type fruity, medium strength described as ripe, fruity, apple) | ||||||||
0-8% | 112-14-1 | 203-939-6 | Acetic Acid Octyl Ester (Octyl Acetate) | Xi; R36/37/38 | FL 3 ATO 5; H226 H303 | 3000 | 5000 | Not determined | Not determined |
(type floral, medium strength described as ripe, green, mushroom, herbal, waxy) | ||||||||
0-4% | 123-35-3 | 204-622-5 | Myrcene | Xi; R10 R36/37/38 R65 | FL 3 ATOT 1 SCI 2 SS 1 EDI 2 EH C2; H226 H304 H315 H317 H319 H412 | 5000 | 5000 | Not determined | Not determined |
(type spicy, high strength described as peppery, terpene, spicy, balsamic, plastic, rosy, celery, carrot) | ||||||||
0-20% | 106-25-2 | 203-378-7 | Nerol | Xi; R36/38 R43 | SCI 2 SS 1B EDI 2A STOT SE3; H315 H317 H318 H319 H335 | 4500 | 5000 | Not determined | Not determined |
(type floral, medium strength described as sweet, natural, neroli, citrus, magnolia, lemon, butter, green, fruity, terpy nuance) | ||||||||
0-15% | 7212-44-4 | 230-597-5 | Nerolidol | Xi N; R36/38 R50/53 | EDI 2 EH A1 EH C1; H319 H400 H410 | 5000 | 5000 | Not determined | Not determined |
(type fruity, medium strength described as sweet, fruity, banana, pineapple, cherry, tropical) | ||||||||
0-4% | 76-22-2 | 200-945-0 | Camphor (Bornan-2-1-one) | F Xi Xn; R11 R20/21/22 R36/37/38 R40 R68/20 | FS 2 ATO 4 ATI 4 STOT SE2; H228 H302 H332 H371 | 1310 | 70 | Not determined | Not determined |
(type camphorous, medium strength described as camphorous) | ||||||||
0-30% | 98-55-5 | 202-680-6 | alpha-Terpineol | Xi; R36/38 | SCI 2 EDI 2A STOT SE3; H315 H319 H335 | 4300 | Not determined | Not determined | Not determined |
(type floral, medium strength described as pine, terpene, lilac, citrus, woody, floral) | ||||||||
0-.02% | 23696-85-7 | 245-833-2 | beta-Damascenones | Xi; R36/37/38 | None | Not Determined | Not Determined | Not determined | Not determined |
C1=-0.003% C2=0.004% C3=0.02% C4=0.02% C5=0.02% C6=0.07% C7=0.008% C8=0.02% C9=0.02% C10=0.02% C11=Not Restricted |
||||||||
0-.02% | 23726-93-4 | 245-844-2 | trans-beta-Damascenones | Xi; R36/37/38 | None | Not Determined | Not Determined | Not determined | Not determined |
C1=-0.003% C2=0.004% C3=0.02% C4=0.02% C5=0.02% C6=0.07% C7=0.008% C8=0.02% C9=0.02% C10=0.02% C11=Not Restricted (type fruity, high strength described as apple, rose, honey, tobacco, sweet) |
||||||||
0-.02% | 23726-91-2 | 245-842-1 | trans-beta-Damascones | Xi; R43 | None | 2920 | Not Determined | Not determined | Not determined |
C1=-0.003% C2=0.004% C3=0.02% C4=0.02% C5=0.02% C6=0.07% C7=0.008% C8=0.02% C9=0.02% C10=0.02% C11=Not Restricted (type fruity, high strength described as fruity, floral, berry, plum, black currant, honey, rose, tobacco, green, woody, minty, herbal, floral) |
||||||||
0-10% | 127-41-3 | 204-841-6 | alpha-Ionone | Xi; R36/38 R42/43 | RES 1 EH C2; H334 H411 | 4590 | 2270 | Not determined | Not determined |
C1=-2% C2=2.6% C3=10.6% C4=31.7% C5=16.7% C6=50.7% C7=5.3% C8=2% C9=5% C10=2.5% C11=Not Restricted (type floral, medium strength described as sweet, woody, floral, violet, orris, tropical, fruity) |
||||||||
0-.2% | 546-80-5 | 208-912-2 | alpha-Thujone | Xi; R22 R36/37/38 | FL 1 ATO 2 ATD 1; H227 H302 H313 | 500 | 362 | Not determined | Not determined |
(type thujonic, medium strength described as cedarleaf) | ||||||||
0-8% | 100-52-7 | 202-860-4 | Benzaldehyde | Xn; R22 | FL 4 ATO 4 SCI 2 EH A2 SS 1 ATI 4 SR 1; H227 H302/332 H315 H317 H334 H401 | 1300 | 5000 | 500 | Not determined |
C1=-0.02% C2=0.02% C3=0.09% C4=0.27% C5=0.14% C6=0.43% C7=0.05% C8=0.6% C9=3% C10=2.5% C11=Not Restricted (type fruity, medium strength described as strong, sharp, sweet, bitter, almond, fruity, powder, nutty, cherry) |
||||||||
0-4% | 4940-11-8 | 225-582-5 | Ethyl Maltol | Xn; R22 | ATO 4; H302 | 1150 | 5000 | Not determined | Not determined |
(type caramelic, high strength described as sweet, caramel, jam, strawberry, cotton candy) | ||||||||
0-8% | 121-33-5 | 204-465-2 | Vanillin | Xi Xn; R22 R36 | EDI 2A EH A3 EH C3; H319 H402 H412 | 1580 | 5010 | 41700 | Not determined |
(type vanilla, medium strength described as sweet, vanilla, creamy, chocolate, phenolic, milky, spicy) | ||||||||
0-.6% | 100-66-3 | 202-876-1 | Anisole | Xi; R10 R38 | FL 3 STOT SE3; H226 H336 | 3700 | Not determined | 5000 | Not determined |
(type phenolic, high strength described as phenolic, gasoline, ethereal, anise) | ||||||||
0-1% | 104-46-1 | 203-205-5 | Anethol | Xi; R10 R38 | None | 2090 | 5000 | Not determined | Not determined |
(type licorice, medium strength described as sweet, anise, licorice) | ||||||||
0-.2% | 140-67-0 | 205-427-8 | Estragole (Turpentine Oil) | Xi Xn N; R10 R36/37/38 R40/22 R43 R51/53 R65 | FL 3 ATO 4 AH 1 ATD 4 SCI 2 SS 1B EDI 2 ATI 4 EH C2; H226 H302 H304 H312 H315 H317 H319 H332 H411 | 1230 | 5000 | Not determined | Not determined |
(type anisic, medium strength described as sweet, sassafrass, anise, spice, green, herbal, minty, weedy, celery) | ||||||||
0-.1% | 89-83-8 | 201-944-8 | Thymol | C N; R20/21/22 R34 R51/53 | ATO 4 EDI 2 EH A2 EH C2; H302 H314 H318 H401 H411 | 980 | 243 | Not determined | Not determined |
(type anisic, medium strength described as sweet, sassafrass, anise, spice, green, herbal, minty, weedy, celery) | ||||||||
0-0.01% | 75-50-3 | 200-875-0 | Trimethyl Amine | F+ Xn C Xi; R12 R20/22 R34 R36/37/38 R41 | FG 1 FL 1 ATO 4 SCI 1B SS 2 EDI 1 EDI 2 ATI 4 STOT SE3; H220 H224 H280 H302 H314 H315 H318 H319 H332 H335 | 500 | 800 | Not determined | Not determined |
(type fishy, very high strength described as fishy, oily, rancid, sweaty, fruity) | ||||||||
0.01% | 110-86-1 | 203-809-9 | Pyridine | F Xn Xi; R11 R20/21/22 R36/38 | FL 2 ATO 4 ATD 4 SCI 2 EDI 2 ATI 4; H225 H302 H312 H315 H319 H320 H332 | 891 | 866 | 28500 | Not determined |
(type fishy, very high strength described as sickening, sour, putrid, fishy, amine) | ||||||||
0-2% | 120-72-9 | 204-420-7 | Indole | : Xn N; R21/22 R37/38 R41 R50/53 | ATO 4 ATD 4 SCI 2 EDI 1 STOT SE3 EH A1 EH C1; H302 H312 H315 H318 H335 H400 H410 | 1000 | 790 | Not determined | Not determined |
(type animal, high strength described as animal, fecal, floral, moth ball, naphthelene, pungent, musty) | ||||||||
0-1% | 111-27-3 | 203-852-3 | 1-Hexanol (Hexan-1-ol) | Xi; R22 | FL 2 FL 3 ATO 4 ATD 4 EDI 1 EDI 2 EH A1 EH C1; H225 H226 H302 H312 H318 H319 H400 H410 | 720 | 3100 | 1060 | Not determined |
(type herbal, medium strength described as ethereal, fusel oil, fruity, alcoholic, sweet, green, pungent) | ||||||||
0-8% | 928-96-1 | 213-192-8 | cis-3-Hex-3-en-1-ol | Xi; R10 R36 | FL 3 EDI 2; H226 H319 | 4700 | 5000 | Not determined | Not determined |
(type green, high strength described as fresh, green, cut grass, foliage, vegetable, herbal, oily, melon rind-like) | ||||||||
0-8% | 89-78-1 | 201-939-0 | Dextro, Laevo(DL)-Menthol | Xi; R37/38 R41 | SCI 2 EDI 1 EDI 2 STOT SE3; H315 H318 H319 H335 | 3180 | Not determined | Not determined | Not determined |
(type mentholic, medium strength described as peppermint, cool, woody) | ||||||||
0-1% | 75-07-0 | 200-836-8 | Acetaldehyde | F+ Xi; R12 R36/37 R40 | FL 1 EDI 2 STOT SE3 CAR 2; H224 H319 H335 H351 | 661 | 640 | Not determined | Not determined |
(type ethereal, high strength described as pungent, ethereal, aldehydic, fruity, fresh, green) | ||||||||
0-.5% | 6789-80-6 | 229-854-4 | cis-3-Hexenal (cisHex-3-enal) | Xi; R10 R22 | FL 3; H226 | 1560 | 3700 | Not determined | Not determined |
(type green, high strength described as green, fatty, grassy, weedy, fruity, apple) | ||||||||
0-.01% | 98-01-1 | 202-627-7 | Furfural (2-Furaldehyde) | Xn T Xi C; R21 R23/25 R36/37/38 R40 | FL 3 ATO 3 ATD 3 SCI 2 EDI 2 ATI 2 STOT SE3 CAR 2 EH C3; H226 H301 H312 H315 H319 H330 H335 H351 H412 | 65 | 148 | 175 | Not determined |
(type bready, medium strength described as sweet, woody, almond, fragrant baked bread, brown, caramelic, nutty, burnt) | ||||||||
0-30% | 6413-10-1 | 229-114-0 | Fructone (Apple Ketal) Methyl Dioxolan | None | None | 5000 | 5000 | Not determined | Not determined |
(type fruity, medium strength described as sweet, fruity, apple, green, tropical, plum, woody) | ||||||||
0-5% | 142-92-7 | Hexyl acetate | Xi; R10 R36/38 | 41500 | 5000 | Not determined | Not determined | |
0-15% | 77-83-8 | Ethyl Methylphenylglycidate | Xi N; R36 R52/53 | 5000 | Not determined | Not determined | Not determined | |
0-5% | 1128-08-1 | Dihydrojasmone | None | 2500 | 5000 | Not determined | Not determined | |
0-.5% | 4312-99-6 | Oct-1-en-3-one | Xi; R10 R22 R36/38 | 175 | 3300 | Not determined | Not determined | |
0-10% | 85213-22-5 | 2-Acetyl-1-Pyrroline | None | Not determined | Not determined | Not determined | Not determined | |
0-1% | 27300-27-2 | 2-Acetyl-3,4,5,6-Tetrahydropyridine | None | Not determined | Not determined | Not determined | Not determined | |
0-1% | 25343-57-1 | 6-Acetyl-2,3,4,5-tetrahydropyridine | None | Not determined | Not determined | Not determined | Not determined | |
0-12% | 107797-26-2 | gamma-Decalactone | Xi; R36/38 | 5000 | 5000 | Not determined | Not determined | |
0-15% | 63357-97-1 | gamma-Nonalactone | None | Not determined | Not determined | Not determined | Not determined | |
0-12% | 698-76-0 | delta-Octalactone | Xi; R36/38 | 5000 | 5000 | Not determined | Not determined | |
0-3% | 34686-71-0 | Jasmine Lactone | Xi; R36/38 | Not determined | Not determined | Not determined | Not determined | |
0-0.01% | 51154-96-2 | Massoia Lactone | Xi | 1890 | Not determined | Not determined | Not determined | |
0-.5% | 182699-77-0 | Wine Lactone | Xi; R36/38 | Not determined | Not determined | Not determined | Not determined | |
0-.5% | 698-10-2 | Maple Furanone | Xi; R22 R36/37/38 | Not determined | Not determined | Not determined | Not determined | |
0-.5% | 28664-35-9 | Caramel Furanone | Xi; R20/22 R36/37 | Not determined | Not determined | Not determined | Not determined | |
0-.1% | 75-08-1 | Ethanethiol, Ethyl Mercaptan | Xn; R12 R20 R50/53 | 682 | Not determined | Not determined | Not determined | |
0-.1% | 71159-90-5 | Grapefruit Mercaptan | Xi; R36/38 | 6000 | Not determined | Not determined | Not determined | |
0-.5% | 74-93-1 | Methanethiol | T N; R12 R23 R50/53 | Not determined | Not determined | Not determined | Not determined | |
0-.1% | 75-66-1 | Tert-butyl Mercaptan | Xi; R12 R36/37 R41 | 8400 | Not determined | Not determined | Not determined | |
0-2% | 2173-57-1 | Nerolin | Xi; R36/38 | 5000 | 5000 | Not determined | Not determined | |
0-1% | 110-01-0 | Tetrahydrothiophene | Xn N; R11 R20/21/22 R36/38 R52/53 | 1200 | Not determined | Not determined | Not determined | |
0-0.01% | 87-40-1 | 2,4,6-Trichloroanisole | Xi | 1890 | Not determined | Not determined | Not determined |
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IMPORTANT
While the descriptions, data and information contained herein are presented in good fath and believed to be accurate, it is provided for your guidance only. Because many factors may affect processing or application/use, we recommend that you perform assessment to determine the suitability of the product for your particular purpose prior to use. Nothing herein should be interpreted as a recommendation to infringe existing trademarks or patents or violate any laws or regulations. No warranties of any kind, either expressed or implied, including fitness for a particular purpose are made regarding the product described. We assume NO responsibility for any injuries resuilting from misuse or misapplication of this product or that might be sustained because of inhalation, ingestion, absorption or other contact with this product. In no case shall the descriptions, information, or data provded be considered a part of our terms and conditions of sale. Further, the descriptions, data and information furnished hereunder are given gratis. No obligation or liability for the description, data and information given are assumed. All such being given and accepted at your risk.
The information on this safety data sheet complies with Annex II of EU REACH Regulation EC 1907/2006, EU REACH Regulation EC 1272/2008.
EU-COMPLIANT SAFETY DATA SHEET
In accordance with REACH Regulation EC No. 1907/2006 & REACH Regulation EC No. 1272/2008
1.1 Product Identifier | Key Note: Pink Peppercorn - INCI: Fragrance |
Harmonization Codes HS: | 330129 Other Essential Oils 330290 Other Mixtures of Odoriferous Substances 330300 Perfumes and Toilet Waters 330730 Perfumed Bath Salts and Other Bath Preparations 330741 Agarbatti and Other Odoriferous Preparations Which Operate By Burning 330749 Other Preparations for Perfuming or Deodorizing Rooms 330790 Depilatories, Other Perfumery, Cosmetic or Toilet Preparations |
1.2 Product Uses and Uses Advised Against: |
Use in Fragrance Products. |
1.3 Manufacturer/Supplier: |
Arts-set Further information obtainable from: Email: contact@arts-set.fr |
1.4 Emergency Telephone Number: | In case of emergency phone 33-0988773206 outside office hours, your local Emergency Room. IF SWALLOWED CALL YOUR POISON CONTROL CENTER |
SECTION 2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture in accordance with paragraph (d) of §1910.1200; | This mixture has not been tested as a whole. The effects, listed below, are based on evaluation of individual components in accordance with the provisions of the regulations(s) noted below and account for all concentrations, SOS, ULTRA and EXTREME and related properties of each concentration. | |
Classification under (EC) Regulation No. 1272/2008 |
Flammable Liquids, Category 3 |
H226: Flammable liquid and vapor. |
Pictograms: | ||
Classification under (EC) Directive 1999/45/EC | ||
Irritating to skin and eyes. May cause sensitization. See Section 15. | ||
Hazard Symbols: Risk Phrases: |
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2.2 Label Elements and Information Concerning Particular Hazards For Human And Environment: | See Section 15. | |
2.3 Classification system: | Directives 67/548/EEC or 1999/45/EC. | |
2.4 Other Hazards: | None. | |
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Chemical Characterization Description: A mixture of fragrance chemicals and/or essentials oils and isolates. 3.2 Dangerous Components:
Substances with Community workplace exposure limits, not listed above: Not Applicable The specific chemical identity and/or exact percentrage (concentration) of composition has been withheld as a trade secret is required. |
SECTION 4. FIRST AID MEASURES
4.1 Description Of First Aid Measures | |
Inhalation: | This material does not present a hazard if inhaled. Remove individual to fresh air and keep at rest in a position comfortable for breathing; as a precautionary measure. Consult a doctor in case of complaints. |
Skin Contact: | Immediately wash with soap and water and rinse thoroughly. Remove soiled clothing. Then consult a doctor. |
Eye Contact: |
Immediately rinse opened eye for several minutes under running water. Rinse cautiously for several minutes, retracting eyelids often. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Remove contact lenses, if present and easy to do. Continue rinsing. Then consult a doctor. |
Swallowing: | Rinse mouth, then make victim drink plenty of water; avoid vomiting (risk of perforation!). Immediately call a doctor. Do not attempt to neutralize. |
4.2 Most Important Symptoms And Effects (Acute or Delayed) | |
Causes skin irritation. May cause an allergic reaction. Causes serious eye damage. |
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4.3 Indication Of Any Immediate Medical Attention And Special Treatment Needed | |
None expected, see Section 4.1 for further information. |
SECTION 5. FIRE FIGHTING MEASURES
5.1 Suitable Extinguishing Agents: | Combustible at elevated termperatures. Use alcohol resistant foam, carbon dioxide, dry chemical, or water spray when fighting first - CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Use fire-extinguishing methods suitable to surrounding conditions. Water or foam may cause frothing if liquid is burning but it still may be a useful extinguishing agent if carefully applied to the fire. Do not direct a water stream directly into the hot burning liquid. |
5.2 Special Hazards Caused By The Substance, Its Products Of Combustion Or Resulting Gases: |
Material may be ignited if preheated to termperatures above the flash point in the presence of a source of ignition. In case of fire, the following can be released: |
5.3 Protective Methods And Equipment For Firefighting: | Do not enter fire area without proper protection including self-contained breathing apparatus, repiratory protective equipment and full protective suit/equipment. Fight fire from a safe distance and a protected location due to the potential of hazardous vapors and decomposition products. |
5.4 Additional Information: | N/A |
SECTION 6. ACCIDENTAL RELEASE MEASURES
6.1 Person-Related Safety Precautions: | Isolate spillage and clean up immediately. Avoid inhalation. Avoid contact with skin and eyes. Refer to Section 7 & Section 8 for protective measures when handling the spillage. |
6.2 Measures For Environmental Protection: | Do not allow liquid to enter drains, surface and ground water, and soil. |
6.3 Measures For Cleaning/Collecting: |
Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose of according to local regulations and according to Section 13. Rinse off area with water. |
6.4 Reference To Other Sections: | Also refer to Section 8 and Section 13. |
SECTION 7. HANDLING AND STORAGE
7.1 Precautions For Safe Handling: |
Observe the general safety regulations when handling chemicals. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation. Avoid inhalation. Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Do not eat, drink or smoke when using this product. Avoid contact with the eyes, skin and mucous membranes. |
7.2 Storage: | Store in original container at or below 25°C. Store in a well ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion -proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. |
7.3 Requirements To Be Met By Storerooms And Receptacles: | Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. |
7.4 Specific End Use(s): | Use in accordance with good manufacturing and industrial hygiene practices. |
SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
8.1 Control Parameters | |
Ingredients With Limit Values That Require Monitoring In The Workplace: | None. |
Additional Information: | N/A |
8.2 Exposure Controls | |
Personal Protective Equipment: |
Wear protective gloves/eye protection/face protection. |
Respiratory Protection: | Under normal conditions of use and where adequate ventilation is available to prevent build up of excessive vapour, this material should not require special engineering controls. However, in conditions of high or prolonged use, or high temperature or other conditions which increase exposure, the following engineering controls can be used to minimize exposure to personnel: a) Increase ventilation of the area with local exhaust ventilation. b) Personnel can use an approved, appropriately fitted respirator with organic vapour cartridge or canisters and particulate filters. c) Use closed systems for transferring and processing this material. Also refer to Sections 2 and Section 7. |
General Protective And Hygienic Measures: |
Follow Good Laboratory and Manufacturing Practices (GLP/GMP). Wash hands before breaks and at the end of work. |
Protection Of Hands: |
Disposable gloves |
Eye Protection: | Safety glasses |
Body Protection: | Lab Coat |
Respiratory Protection: | NIOSH-approved organic vapor respiration or equivalent. |
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
General Information
Appearance/Form: | Liquid |
Color: | Clear to Brown |
Odor: | To match standard. Scent character: A Mobile Liquid with odor. Why Pink Peppercorn is a Key Note: Any and all pepper notes should be present in a true fragrance library. Not only is it spicy and sensitive, it is also mysterious and dark. It brings a classy, yet underground finish to any perfume. Important Free Sample Policy Note: Due to the high cost of raw materials associated with this rare and high end fragrance note, we are unable to provide free samples. If requested in a Free Sampler Pack during checkout, we will replace with an alternate substitution. We are sorry for the inconvenience and thank you for your understanding. |
Change In Condition | |
Melting Point/Melting Range: | Not determined |
Boiling Point/Boiling Range: | Not determined |
Flashpoint (°F): | SOS: 230°F ULTRA: 198°F EXTREME: 167. If not listed, please call for flashpoint(s). |
Self-Igniting: | Will not self-ignite. |
Danger Of Explosion: | Does not present an explosion hazard. |
Vapor Pressure: | >0.0009 mm Hg @ 20°C |
Density at 25°C: | 0.975-1.2 g/cc |
Solubility In/Miscibility With Water: | No |
pH-value At 20°C: | Not determined |
Octonol/Water Partition Coefficient: | 4.1 - 9.3 at 25°C 4.7 |
Volatiles, % By Weight: | 5.1-6.7 |
Bulk Density: | 321.8 - 410.1 |
Other Information: | None. |
SECTION 10. STABILITY AND REACTIVITY
Reactivity: | Presents no significant reactivity hazard, by itself, or in contact with water. |
Stability: | Stable when stored in accordance with the recommended storage conditions. |
Materials To Be Avoided: |
Avoid contact with strong acids, alkalis or oxidising agents. |
Hazardous Reactions: | No dangerous reactions known. Not expected under normal conditions of use. |
Conditions To Avoid: | Avoid extreme heat. |
Hazardous Decomposition Products: | CO2, CO |
SECTION 11. TOXICOLOGICAL INFORMATION
11.1 Information On Toxicological Effects This mixture has not been tested as a whole for health effects. The health effects have been calculated using the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC, in accordance with Regulation (EC) No 1907/2006 (REACH). In addition, toxicity information for the mixture, if available, is provided below in accordance with methods given in Regulation (EC) No 1272/2008. |
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Acute Toxicity (LD/LC50) Values Relevant For Classification:: |
Calculated LD50: 1.2 - 1.7 g/kg |
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Assumed Toxicity Value (LD50 or ATE) for Acute Oral Toxicity: | 3471.45 - 4209.26 | ||||||||||||||||||||||||||||
Assumed Toxicity Value (LD50 or ATE) for Acute Dermal Toxicity: | 9398.1 - 14159.34 | ||||||||||||||||||||||||||||
Assumed Toxicity Value (LC50 or ATE) for Acute Inhalation Toxicity: | Not available | ||||||||||||||||||||||||||||
Inhalation Route: | Not available | ||||||||||||||||||||||||||||
Primary Effects: |
After skin contact: Irritation. Chronic exposure may cause damage to skin and kidneys. |
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Information about hazardous ingredients in the mixture: | |||||||||||||||||||||||||||||
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SECTION 12. ECOLOGICAL INFORMATION
12.1 Toxicity: | Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. See Section 15. |
12.2 Persistence And Degradability: | Not determined. |
12.3 Bioaccumulative Potential: | Not determined. |
12.4 Mobility In Soil: | Not determined. |
12.5 Results of PBT and vPvB Assessment: | This substance does not meet the PBT/vPvB criteria of REACH, Annex XIII. |
12.6 Other Adverse Effects: | Not determined. |
SECTION 13. DISPOSAL CONSIDERATIONS
13.1 Product: |
Chemical residues and remains should be routinely handled as special waste. This must be disposed of incompliance with anti-pollution and other laws of the country concerned. To ensure compliance we recommend that you contact the relevant (local) authorities and/or an approved waste-disposal company for information. |
13.2 European Waste Catalogue: | 07 07 04 other organic solvents, washing liquids and mother liquors |
13.3 Packaging: | Disposal must be made in accordance with local waste management regulations. Contaminated packaging must be disposed of in the same manner as the product. Non-contaminated packaging materials may be recycled. Contact your local service providers for further information. |
13.4 Disposal Methods: | DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State, Provincial, and local laws and regulations. Regulations vary in different locations. Waste characterizations and compliance with applicable laws are the sole responsibility of the waste generator. As your suuplier, we have no control over the management practices or manufacturing processes of parties handling or using this material. The information presented here pertains only to the product when used as intended, according to this Safety Date Sheet. For unused and uncontaminated product, the preferred options include sending to a licensed and permitted incinerator or other thermal destruction device. Various federal, state or provincial agencies may have specific regulations concerning the transportation, handling, storage, use or disosal of this product which may not be covered in the Safety Data Sheet. The user shall have to review these regulations to ensure full compliance with all applicable regulations. |
SECTION 14. TRANSPORTATION INFORMATION
14.1 UN number: |
UN3082 |
14.2 UN Proper Shipping Name: | ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. |
Flashpoint (°F): | SOS: 230°F ULTRA: 198°F EXTREME: 167°F. If not listed, please call for flashpoint(s). |
14.3 Transport Hazard Class(es): | 9: 100-140°F (Flammable), 3A: 140-200°F (Combustible). 3B: >200°F (Not Regulated) |
Road/Rail (CDGRR ADR, RID): Not Restricted |
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Sub Risk: | - |
14.4. Packing Group: | III |
14.5 Environmental Hazards: | This is an environmentally hazardous substance. |
14.6 Special precautions for user: | None additional |
14.7 Transport In Bulk According To Annex II Of MARPOL73/78 And The IBC Code: | Not applicable |
SECTION 15. REGULATORY INFORMATION
15.1 TSCA Status & Safety, Health And Environmental Regulations/Legislation Specific For The Substance Or Mixture: |
All components in this product are on the TSCA Inventory. None Additional.
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15.2 Chemical Safety Assessment | A Chemical Safety Assessment has not been carried out for this product. |
15.3 Labeling According To EU Guidelines: | Code letter and hazard designation of product: Xi, Irritant Xn, Harmful N, Dangerous for the environment |
15.4 Hazard-Determining Components Of Labeling: | See Section 3 |
15.5 Risk Phrases(R): |
10 Flammable. |
15.6 Safety Phrases(S): |
02 Keep out of reach of children. |
15.7 Class And Category Of Danger: |
Flammable Liquid: Hazard Category 3 |
15.8 Signal Word: | Warning, Danger |
15. 9 Hazard Phrases(H): | 226 Flammable liquid and vapour. 303 May be harmful if swallowed. 304 May be fatal if swallowed and enters airways. 313 Maybe be harmful in contact with skin. 315 Causes skin irritation. 317 May cause an allergic skin reaction. 318 Causes serious eye damage. 333 May be harmful if inhaled. 410 Very toxic to aquatic life with long lasting effects. 412 Harmful to aquatic life with long lasting effects. |
Supplemental Information: | No Animal testing. No animal products or byproducts are used in this fragrance. May produce an allergic reaction. |
Precautionary Statements(P): | 210 Keep away from heat, sparks, open flames and hot surfaces. - No smoking. 233 Keep container tightly closed. 240 Ground/bond container and receiving equipment. 241 Use explosion-proof electrical ventilating and lighting equipment. 242 Use only non-sparking tools. 243 Take precautionary measures against static discharge. 261 Do not breathe vapour or dust. 264 Wash hands and other contacted skin thoroughly after handling. 272 Contaminated work clothing should not be allowed out of the workplace. 273 Avoid release to the environment. 280 Wear protective gloves/eye protection/face protection. 301/330/331 IF SWALLOWED: Rinse mouth. Do not induce vomiting. 302/352 IF ON SKIN: Wash with plenty of soap and water. 302/303/361/353 IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. 304/340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. 305/351/338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contactlenses, if present and easy to do. Continue rinsing. 310 Immediately call a POISON CENTER or doctor/physician. 333/313 If skin irritation or rash occurs: Get medical advice/attention. 362 Take off contaminated clothing and wash before reuse. 363 Wash contaminated clothing before reuse. 370/378 In case of fire: Use carbon dioxide, dry chemical, foam for extinction. 391 Collect Spillage. 403/235 Store in a well-ventilated place. Keep cool. 405 Store locked up. 501 Dispose of contents/container to approved disposal site, in accordance with local regulations. |
Pictograms: | |
Other Hazards: | None |
Concentration % Limits | EH A1= 90.20% EH C1=90.20% EH C2=9.02% EH C3=0.92% EH C4=10% SCI 1A=90.02% SCI 2=47.50% SS 1=4.74% |
Total Fractional Values | EH A1= 1.16 EH C1=1.16 EH C2=11.52 EH C3=115.47 EH C4=10.90 SCI 1A=4.93 SCI 2=2.60 SS 1=26.00 |
Key To Revisions: | Not applicable. |
Key To Abbreviations: |
AH 1 Aspiration - Hazard Category 1 |
SECTION 16. OTHER INFORMATION
This information is based on use of product neat, and not use of product in project bases, but on use as a fragrance concentrate. For detailed information on the categories below, please refer to the IFRA QRA Information Booklet.
Table 1: SAF and Product Type Consumer Exposure Levels that Drive the IFRA QRA Category
IFRA QRA Category
|
SAF
|
Category Consumer Exposure*
mg/cm2/day |
Product Type That Drives the Category Consumber Exposure Level
|
Minimum Pragmatic Level
|
Category 1 (C1)
|
300
|
11.7
|
Lip Products
|
Not Necessary
Acceptable Exposure Level derived from IFRA QRA |
Category 2 (C2)
|
300
|
9.1
|
Deodorants/Antiperspirants
|
Not Necessary
Acceptable Exposure Level derived from IFRA QRA |
Category 3 (C3)
|
300
|
2.2
|
Hydroalcoholics for Shaved Skin
|
Not Necessary
Acceptable Exposure Level derived from IFRA QRA |
Category 4 (C4)
|
100
|
2.2
|
Hydroalcoholics for Unshaved Skin
|
Not Necessary
Acceptable Exposure Level derived from IFRA QRA |
Category 5 (C5)
|
100
|
4.2
|
Hand Cream
|
Not Necessary
Acceptable Exposure Level derived from IFRA QRA |
Category 6 (C6)
|
100
|
1.4
|
Mouthwash
|
Not Necessary
Acceptable Exposure Level derived from IFRA QRA |
Category 7 (C7)
|
300
|
4.4
|
Intimate Wipes
|
Not Necessary
Acceptable Exposure Level derived from IFRA QRA |
Category 8 (C8)
|
100
|
1.0
|
Hair Styling Aids
|
2% The maximum concentration will not exceed 2% and may be lower if determined by the IFRA QRA
|
Category 9 (C9)
|
100
|
0.2
|
Rinse-off Hair Conditioners
|
5% The maximum concentration will not exceed 5% and may be lower if determined by the IFRA QRA
|
Category 10 (C10)
|
100
|
0.1
|
Hard Surface Cleaners
|
2.5% The maximum concentration will not exceed 2.5% and may be lower if determined by the IFRA QRA
|
Category 11 (C11)
|
10
|
0.00033
|
Candles
|
Due to the expected negligible skin exposure from such products the risk of induction of dermal sensitization through the normal formulation and use of such products is considered to be negligible. As such, the concentration of fragrance ingredient is not restricted in the finished product.
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* The Category Consumer Exposure Level (mg/cm2/day) is driven by the product type in that category with the combined highest consumer exposure level and highest Sensitization Assessment Factor (SAF). In order to identify the product type consumer exposure that drives the category consumer exposure, please refer to the Technical Dossier, Table 9 in the IFRA QRA Information Booklet.
Table 2: Components-Allergens***
Level | CAS Nr | EC Nr |
Substance |
R Phrase: Classification for |
Classification for
(CLP) 1272/2008 |
LD50/ATE Oral |
LD50/ATE |
LC50/ATE
Inhalation |
LC50 Route |
0-0.5% | 122-40-7 | 204-541-5 |
alpha-Amyl Cinnamic Aldehyde | Xi; R21/41 R38 R43 | SS 1B EH C2; H317 H411 | 3730 | Not determined | Not determined | Not determined |
C1=0.02% C2=0.02% C3=0.05% C4=0.05% C5=0.05% C6=0.4% C7=.04% C8=.05% C9=.05% C10=.05% C11=Not Restricted (type floral, medium strength described as sweet, floral, oily, fruity, herbal, jasmin, tropical, green, powdery, waxy) |
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0-2.5% | 100-51-6 | 202-859-9 | Benzyl Alcohol | Xn, R20/R22 | ATO 4 EDI 2 ATI 4; H302 H319 H332 | 1040 | 2000 | 1000 | Not determined |
C1=0.2% C2=0.2% C3=0.9% C4=2.7% C5=1.4% C6=4.3% C7=0.4% C8=.2.0% C9=5.0% C10=2.5% C11=Not Restricted (type floral, medium strength described as floral, rose, balsamic, sweet, fruity, chemical) |
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0-0.4% | 104-54-1 | 203-212-3 |
Cinnamic Alcohol | None | SCI 2 EDI 2; H315 H319 | 2000 | >5000 | Not determined | Not determined |
C1=0.09% C2=0.1% C3=0.4% C4=0.4% C5=0.4% C6=2.2% C7=0.2% C8=.0.2% C9=0.4% C10=0.4% C11=Not Restricted (type balsamic, medium strength described as sweet, balsam, hyacinth, spicy, green, powdery, cinnamic, floral, yeasty) |
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0-5% | 5392-40-5 | 226-394-6 |
Citral | Xi; R38 R43 | SCI 2 SS 1B EDI 2; H315 H317 H319 | 4960 | 2250 | Not determined | Not determined |
C1=0.04% C2=0.05% C3=0.2% C4=0.6% C5=0.3% C6=1% C7=0.1% C8=.1.4% C9=5% C10=2.5% C11=Not Restricted (type citrus, medium strength described as sharp, lemon, sweet, tangy, green, citrus, juicy, lime, woody, herbal) |
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0-.4.3% | 97-53-0 | 202-589-1 |
Eugenol | Xn Xi; R36 R43 | SS 1B EDI 2; H317 H319 | 1930 | 5000 | 2580 | Not determined |
C1=0.2% C2=0.2% C3=0.5% C4=0.5% C5=0.5% C6=4.3% C7=0.4% C8=.0.5% C9=0.5% C10=0.5% C11=Not Restricted (type spicy, medium strength described as sweet, spicy, close, woody, allspice) |
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0-3.6% | 107-75-5 | 203-518-7 |
7-Hydroxy-Citronellal | Xi; R36, R43 | SS 1B EDI 2; H317 H319 | 5000 | 2000 | Not determined | Not determined |
C1=0.1% C2=0.2% C3=0.8% C4=1.0% C5=1.0% C6=3.6% C7=0.4% C8=1% C9=1% C10=1% C11=Not Restricted (type floral, medium strength described as floral, lily, sweet, green, waxy, tropical, melon) |
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0-0.2% | 97-54-1 | 202-590-7 |
Isoeugenol | Xi; R21/41 R38 R43 | SS 1B EDI 2; H317 H319 | 1560 | Not Determined | Not determined | Not determined |
C1=0.01% C2=0.01% C3=0.02% C4=0.02% C5=0.02% C6=0.2% C7=0.02% C8=0.02% C9=0.02% C10=0,02% C11=Not Restricted (type spicy, medium strength described as sweet, spicy, clove, woody, carnation, floral) |
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0-3.5% | 101-85-9 | 202-982-8 |
alpha-Amyl Cinnamic Alcohol | Xi; R21/41 R38 R43 | SS 1B EDI 2; H317 H319 | 4000 | >5000 | Not determined | Not determined |
C1=0.02% C2=0.03% C3=0.11% C4=0.32% C5=0.17% C6=0.51% C7=0.05% C8=0.07% C9=3.5% C10=2.5% C11=Not Restricted (type spicy, medium strength, floral, jasmine, rosy, waxy, sweet spicy, woody, cinnamon nuance) |
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0-12.8% |
118-58-1 | |
Benzyl Salicylate |
Xi N; R43 R51/53 |
SS 1B EDI 2 ETO C3; H317 H319 H412 |
2227 |
Not determined |
Not determined | Not determined |
C1=0.5% C2=0.7% C3=2.7% C4=8% C5=4.2% C6=12.8% C7=1.3% C8=2% C9=5% C10=2.5% C11=Not Restricted (type balsamic, low strength, described as balsam, clean, herbal, oily, sweet) |
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0-.4% | 104-55-2 | 203-213-9 |
Cinnamic Aldehyde | None | ATD 4 SS 1 SCI 2 EDI 2; H312 H315 H317 H319 | 2220 | .59 | .Not determined | Not determined |
C1=0.02% C2=0.02% C3=0.05% C4=0.05% C5=0.05% C6=0.4% C7=0.04% C8=0.05% C9=0.05% C10=0.05% C11=Not Restricted (type spicy, high strength, described as sweet, spice, cinnamon, red hots, warm) |
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0-5% | 91-64-5 | 202-086-7 |
Coumarin | Xn N; R20/21/22 R43 R51/53 | ATO 4 SS 1 ETO C3; H302 H317 H412 | 293 | 242 | Not determined | Not determined |
C1=0.1% C2=0.13% C3=0.5% C4=1.6% C5=0.8% C6=2.5% C7=0.3% C8=2% C9=5% C10=2.5% C11=Not Restricted (type tonka, medium strength, described as sweet, hay, tonka, new mown hay) |
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0-8.6% | 106-24-1 | 203-377-1 |
Geraniol | Xi; R38 R41 R43 | SCI 2 SS 1 EDI 1; H315 H317 H318 | 3600 | 5000 | Not determined | Not determined |
C1=0.3.% C2=0.4% C3=1.8% C4=5.3% C5=2.8% C6=8.6% C7=0.9% C8=2% C9=5% C10=2.5% C11=Not Restricted (type floral, medium strength, described as sweet, floral, fruity, rose, waxy, peach, citrus) |
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0-0.2% | 31906-04-4 | 250-863-4 |
HMPCC (Lyrall) | Xi; R43 | SS 1B; H317 | 3250 | 11300 | Not determined | Not determined |
C1=0.02.% C2=0.02% C3=0.2% C4=0.2% C5=0.2% C6=0.2% C7=0.02% C8=0.2% C9=0.2% C10=0.2% C11=Not Restricted (type floral, medium strength, described as floral, muguet, cyclamen, rhubarb, woody) |
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0-5% | 105-13-5 | 203-273-6 |
(4-Methoxybenzyl) Anysil Alcohol | None | SCI 1B EDI 1; H315 H318 | 1340 | 3000 | Not determined | Not determined |
C1=0.04.% C2=0.1% C3=0.2% C4=0.7% C5=0.4% C6=1.1% C7=0.1% C8=1.5% C9=5% C10=2.5% C11=Not Restricted (type powdery, medium strength, described as sweet, powdery, hawthorn, lilac, rose, floral, hyacinth, creamy, balsamic, coumarin, cherry, vanilla, licorice, anise) |
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0-5% | 103-41-3 | 203-109-3 |
Benzyl Cinnamate | None | SCI 1B EDI 1; H315 H318 | 5530 | >3000 | Not determined | Not determined |
C1=0.1.% C2=0.2% C3=0.7% C4=2.1% C5=1.1% C6=3.4% C7=0.4% C8=2% C9=5% C10=2.5% C11=Not Restricted (type balsamic low strength, described as sweet, balsamic, floral, fruity, cherry, spicy, powdery) |
||||||||
0-5% | 4602-84-0 | 225-004-1 |
Farnesol | None | EDI 2 EH A1 ETO C1; H319 H400 H410 | 6000 | >5000 | Not determined | Not determined |
C1=0.08.% C2=0.11% C3=0.4% C4=1.2% C5=0.6% C6=2% C7=0.2% C8=2% C9=5% C10=2.5% C11=Not Restricted (type floral low strength, described as mild, fresh, sweet, linden, floral, angelica) |
||||||||
0-3% | 80-54-6 | 201-289-8 |
2-(4-tert-Butylbenzyl) Propionaldehyde (Lilyall/BMHCA) | Xn Xi N; R22 R38 R43 R51/53 R61 R62 | ATO 4 SS 1B SCI 2 REP 2 ETO C2; H302 H315 H317 H361 H411 | 1390 | >5000 | Not determined | Not determined |
C1=0.1.% C2=0.2% C3=0.6% C4=1.9% C5=1% C6=3% C7=0.3% C8=2% C9=2.5% C10=2.5% C11=Not Restricted (type floral medium strength, described as floral, muguet, watery, green, powdery, cumin) |
||||||||
0-12% | 78-70-6 | 201-134-4 |
Linalool | Xi; R38 | SCI 2 EDI 2; H315 H319 | 2200 | 5610 | Not determined | Not determined |
C1=1% C2=2% C3=2% C4=1% C5=5% C6=2% C7=1% C8=2% C9=12% C10=5% C11=Not Restricted (type floral medium strength, described as citrus, floral, sweet, bois de rose, woody, green, blueberry) |
||||||||
0-42.8% | 120-51-4 | 204-402-9 |
Benzyl Benzoate | Xn N; R22 R51/53 | ATO 4 EH C1 ETO C3; H302 H400 H411 H412 | 1700 | 4000 | Not determined | Not determined |
C1=1.7% C2=2.2% C3=8.9% C4=26.7% C5=14% C6=42.8% C7=4.5% C8=2% C9=5% C10=2.5% C11=Not Restricted (type balsamic low strength, described as faint, sweet, balsam, oily, herbal, fruity) |
||||||||
0-13.3% | 106-22-9 | 203-375-0 |
Citronellol | Xi N; R36/38 R43 R51/53 | SCI 2 EDI 2 SS 1B; H315 H317 H319 | 3450 | 2650 | Not determined | Not determined |
C1=0.8% C2=1.1% C3=4.4% C4=13.3% C5=7% C6=21.4% C7=2.2% C8=2% C9=5% C10=2.5% C11=Not Restricted (type citrus, medium strength described as sweet, green, citrus, rose, woody, herbal) |
||||||||
0-17.1% | 101-86-0 | 202-983-3 | alpha-Hexyl Cinnamic Aldehyde | Xi N; R38 R43 R50/53 | SS 1; H317 | 3100 | Not determined | Not determined | Not determined |
C1=0.7% C2=0.9% C3=3.6% C4=10.7% C5=5.6% C6=17.1% C7=1.8% C8=2% C9=5% C10=2.5% C11=Not Restricted (type floral, medium strength described as fresh, floral, green, jasmin, herbal, waxy, citrus, fruity) |
||||||||
0-20% | 5989-27-5 | 227-813-5 |
dextro-Limonene (R)-p-Mentha-1,8-diene |
Xi N; R10 R38 R43 R50/53 R65 | FL 3 AH 1 SCI 2 SS 1B EH A1 ETO C1; H226 H304 H315 H317 H400 H410 | >5000 | >5000 | Not determined | Not determined |
C1=1.4% C2=1.9% C3=4.6% C4=12.7% C5=6% C6=20% C7=2.8% C8=3% C9=7% C10=3.5% C11=Not Restricted (type citrus, medium strength described as citrus, orange fresh sweet) |
||||||||
0-0.08% | 111-12-6 | 203-836-6 |
Methyl Heptine Carbonite | Xi; R21/41 R38 R43 | SS 1B EDI 2; H317 H319 | 1530 | 3300 | Not determined | Not determined |
C1=0.003% C2=0.004% C3=0.01% C4=0.01% C5=0.01% C6=0.08% C7=0.008% C8=0.01% C9=0.01% C10=0.01% C11=Not Restricted (type green, high strength described as green, leafy, waxy, violet, cucumber) |
||||||||
0-50.7% | 127-51-5 | 204-846-3 |
alpha-Isomethyl Ionone | Xi N; R36/38 R51/53 | SCI 2 EDI 2 ETO C2; H315 H319 H411 | >5000 | >5000 | Not determined | Not determined |
C1=2% C2=2.6% C3=10.6% C4=31.7% C5=16.7% C6=50.7% C7=5.3% C8=2% C9=5% C10=2.5% C11=Not Restricted (type floral, medium strength described as woody, violet, floral) |
||||||||
0-0.5% | 90028-67-4 | 289-860-8 |
Treemoss Extract | Xi; R21/41 R38 R43 | SS 1B EDI 2; H317 H319 | 4330 | >5000 | Not determined | Not determined |
C1=-0.02% C2=0.03% C3=0.1% C4=0.1% C5=0.1% C6=0.5% C7=0.1% C8=0.1% C9=0.1% C10=0.1% C11=Not Restricted (type woody, medium strength described as woody, tar) |
||||||||
0-0.5% | 90028-68-5 | 289-861-3 |
Oakmoss Extract | Xi; R21/41 R38 R43 | SS 1B EDI 2; H317 H319 | 4330 | >5000 | Not determined | Not determined |
C1=-0.02% C2=0.03% C3=0.1% C4=0.1% C5=0.1% C6=0.5% C7=0.1% C8=0.1% C9=0.1% C10=0.1% C11=Not Restricted (type mossy, medium strength described as oakmoss) |
*** These ingredients appear on the list of substances in Annex III of Regulation (EC) No. 1223/2009 on cosmetic products and Annex III Part 1 of Council Directive 76/768/ECC with amendments of Cosmetic Directive 2008/42/EC of 3 April 2008 as referred to by Regulation (EC) No. 648/2004 on detergents.
Table 3: Components-Common
Level | CAS Nr | EC Nr |
Substance |
R Phrase: Classification for |
Classification for
(CLP) 1272/2008 |
LD50/ATE Oral |
LD50/ATE |
LC50/ATE
Inhalation |
LC50 Route |
0-25.7% | 2050-08-0 | 218-080-2 |
Hexyl (Amyl) Salicylate | Xi Xn N; R22 R38 R43 R50/53 R51/53 | H315 H317 H410 |
2000 |
Not determined |
Not determined | Not determined |
C1=-1% C2=1.3% C3=5.3% C4=16% C5=8.4% C6=25.7% C7=2.7% C8=2% C9=5% C10=2.5% C11=Not Restricted (type floral, medium strength described as herbal, floral, clover, azalea, sweet, chocolate) |
||||||||
0-10% | 107-31-3 | 203-481-7 | Methyl Formate | F+ Xn Xi; R12 R20/22 R36/37 | FL 1 ATO 4 ATD 3 EDI 2 EDI 2A SCI 2 ATI 4 STOT SE3 STOT SE1; H224 H301 H302 H311 H319 H331 H332 H335 H370 | 1500 | 4000 | Not determined | Not determined |
C1=-0.03% C2=0.04% C3=0.1% C4=0.1% C5=0.1% C6=0.8% C7=0.08% C8=0.1% C9=0.1% C10=0.1% C11=Not Restricted (type fruity, medium strength described as fruity, plum) |
||||||||
0-5% | 79-20-9 | 201-185-2 | Methyl Acetate | F Xi Xn T; R11 R20/21/22 R36 R39/23/24/25 R66 R67 | FL 2 ATO 4 ATD 4 EDI 2 STOT SE3 STOT SE1; H225 H302 H312 H319 H332 H336 H370 | 5000 | 5000 | Not determined | Not determined |
C1=-0.07% C2=0.08% C3=0.35% C4=1.04% C5=0.55% C6=1.67% C7=0.17% C8=2% C9=5% C10=2.5% C11=Not Restricted (type ethereal, medium strength described as ether, sweet, fruity, solvent-like, green, fresh, rum, cognac, whiskey) |
||||||||
0-2% | 623-42-7 | 210-792-1 | Methyl Butyrate (Methyl Butanoate) |
F Xn Xi; R11 R20 R36/37/38 | FL 2 | 5000 | 3560 | 18000 | Not determined |
(type fruity, medium strength described as fruity, apple, sweet, pineapple, banana) | ||||||||
0-10% | 141-78-6 | 205-500-4 | Ethyl Ethanoate (Ethyl Acetate) | F Xi Xn T; R10 R11 R20/21/22 R36 R39/23/24/25 R66 R67 R68/20/21/22 | FL 2 EDI 2 STOT SE3; H225 H319 H336 | 5620 | 5000 | 200000 | Not determined |
(type ethereal, high strength described as ethereal, fruity, sweet, weedy, green, rum-like, cherry) | ||||||||
0-8% | 105-54-4 | 203-306-4 | Ethyl Butyrate (Ethyl Butanoate) |
Xi; R10 R36/37/38 | FL 3 SCI 2 EDI 2A STOT SE3; H226 H315 H319 H335 H373 | 13000 | 2000 | Not determined | Not determined |
(type fruity, high strength described as fruity, juicy, sweet, pineapply, cognac, tutti frutti, apple ethereal) | ||||||||
0-25% | 123-92-2 | 204-662-3 | Isoamyl Acetate (Isopentyl Acetate) | Xi; R10 R66 | FL 3 STOT SE3 EH A1; H226 H335 H402 | 16600 | 5000 | Not determined | Not determined |
(type fruity, high strength described as sweet, banana, fruity, estry) | ||||||||
0-8% | 540-18-1 | 208-739-2 | Amyl Butyrate Pentyl Butanoate |
Xi; R36/37/38 | None | 12200 | Not Determined | Not determined | Not determined |
(type fruity, medium strength described as sweet, banana, fruity, cherry, pineapple, tropical) | ||||||||
0-3% | 2173-56-0 | 218-528-7 | Amyl Valerate (Pentyl Pentanoate) | None | None | 35420 | Not determined | Not determined | Not determined |
(type fruity, medium strength described as ripe, fruity, apple) | ||||||||
0-8% | 112-14-1 | 203-939-6 | Acetic Acid Octyl Ester (Octyl Acetate) | Xi; R36/37/38 | FL 3 ATO 5; H226 H303 | 3000 | 5000 | Not determined | Not determined |
(type floral, medium strength described as ripe, green, mushroom, herbal, waxy) | ||||||||
0-4% | 123-35-3 | 204-622-5 | Myrcene | Xi; R10 R36/37/38 R65 | FL 3 ATOT 1 SCI 2 SS 1 EDI 2 EH C2; H226 H304 H315 H317 H319 H412 | 5000 | 5000 | Not determined | Not determined |
(type spicy, high strength described as peppery, terpene, spicy, balsamic, plastic, rosy, celery, carrot) | ||||||||
0-20% | 106-25-2 | 203-378-7 | Nerol | Xi; R36/38 R43 | SCI 2 SS 1B EDI 2A STOT SE3; H315 H317 H318 H319 H335 | 4500 | 5000 | Not determined | Not determined |
(type floral, medium strength described as sweet, natural, neroli, citrus, magnolia, lemon, butter, green, fruity, terpy nuance) | ||||||||
0-15% | 7212-44-4 | 230-597-5 | Nerolidol | Xi N; R36/38 R50/53 | EDI 2 EH A1 EH C1; H319 H400 H410 | 5000 | 5000 | Not determined | Not determined |
(type fruity, medium strength described as sweet, fruity, banana, pineapple, cherry, tropical) | ||||||||
0-4% | 76-22-2 | 200-945-0 | Camphor (Bornan-2-1-one) | F Xi Xn; R11 R20/21/22 R36/37/38 R40 R68/20 | FS 2 ATO 4 ATI 4 STOT SE2; H228 H302 H332 H371 | 1310 | 70 | Not determined | Not determined |
(type camphorous, medium strength described as camphorous) | ||||||||
0-30% | 98-55-5 | 202-680-6 | alpha-Terpineol | Xi; R36/38 | SCI 2 EDI 2A STOT SE3; H315 H319 H335 | 4300 | Not determined | Not determined | Not determined |
(type floral, medium strength described as pine, terpene, lilac, citrus, woody, floral) | ||||||||
0-.02% | 23696-85-7 | 245-833-2 | beta-Damascenones | Xi; R36/37/38 | None | Not Determined | Not Determined | Not determined | Not determined |
C1=-0.003% C2=0.004% C3=0.02% C4=0.02% C5=0.02% C6=0.07% C7=0.008% C8=0.02% C9=0.02% C10=0.02% C11=Not Restricted |
||||||||
0-.02% | 23726-93-4 | 245-844-2 | trans-beta-Damascenones | Xi; R36/37/38 | None | Not Determined | Not Determined | Not determined | Not determined |
C1=-0.003% C2=0.004% C3=0.02% C4=0.02% C5=0.02% C6=0.07% C7=0.008% C8=0.02% C9=0.02% C10=0.02% C11=Not Restricted (type fruity, high strength described as apple, rose, honey, tobacco, sweet) |
||||||||
0-.02% | 23726-91-2 | 245-842-1 | trans-beta-Damascones | Xi; R43 | None | 2920 | Not Determined | Not determined | Not determined |
C1=-0.003% C2=0.004% C3=0.02% C4=0.02% C5=0.02% C6=0.07% C7=0.008% C8=0.02% C9=0.02% C10=0.02% C11=Not Restricted (type fruity, high strength described as fruity, floral, berry, plum, black currant, honey, rose, tobacco, green, woody, minty, herbal, floral) |
||||||||
0-10% | 127-41-3 | 204-841-6 | alpha-Ionone | Xi; R36/38 R42/43 | RES 1 EH C2; H334 H411 | 4590 | 2270 | Not determined | Not determined |
C1=-2% C2=2.6% C3=10.6% C4=31.7% C5=16.7% C6=50.7% C7=5.3% C8=2% C9=5% C10=2.5% C11=Not Restricted (type floral, medium strength described as sweet, woody, floral, violet, orris, tropical, fruity) |
||||||||
0-.2% | 546-80-5 | 208-912-2 | alpha-Thujone | Xi; R22 R36/37/38 | FL 1 ATO 2 ATD 1; H227 H302 H313 | 500 | 362 | Not determined | Not determined |
(type thujonic, medium strength described as cedarleaf) | ||||||||
0-8% | 100-52-7 | 202-860-4 | Benzaldehyde | Xn; R22 | FL 4 ATO 4 SCI 2 EH A2 SS 1 ATI 4 SR 1; H227 H302/332 H315 H317 H334 H401 | 1300 | 5000 | 500 | Not determined |
C1=-0.02% C2=0.02% C3=0.09% C4=0.27% C5=0.14% C6=0.43% C7=0.05% C8=0.6% C9=3% C10=2.5% C11=Not Restricted (type fruity, medium strength described as strong, sharp, sweet, bitter, almond, fruity, powder, nutty, cherry) |
||||||||
0-4% | 4940-11-8 | 225-582-5 | Ethyl Maltol | Xn; R22 | ATO 4; H302 | 1150 | 5000 | Not determined | Not determined |
(type caramelic, high strength described as sweet, caramel, jam, strawberry, cotton candy) | ||||||||
0-8% | 121-33-5 | 204-465-2 | Vanillin | Xi Xn; R22 R36 | EDI 2A EH A3 EH C3; H319 H402 H412 | 1580 | 5010 | 41700 | Not determined |
(type vanilla, medium strength described as sweet, vanilla, creamy, chocolate, phenolic, milky, spicy) | ||||||||
0-.6% | 100-66-3 | 202-876-1 | Anisole | Xi; R10 R38 | FL 3 STOT SE3; H226 H336 | 3700 | Not determined | 5000 | Not determined |
(type phenolic, high strength described as phenolic, gasoline, ethereal, anise) | ||||||||
0-1% | 104-46-1 | 203-205-5 | Anethol | Xi; R10 R38 | None | 2090 | 5000 | Not determined | Not determined |
(type licorice, medium strength described as sweet, anise, licorice) | ||||||||
0-.2% | 140-67-0 | 205-427-8 | Estragole (Turpentine Oil) | Xi Xn N; R10 R36/37/38 R40/22 R43 R51/53 R65 | FL 3 ATO 4 AH 1 ATD 4 SCI 2 SS 1B EDI 2 ATI 4 EH C2; H226 H302 H304 H312 H315 H317 H319 H332 H411 | 1230 | 5000 | Not determined | Not determined |
(type anisic, medium strength described as sweet, sassafrass, anise, spice, green, herbal, minty, weedy, celery) | ||||||||
0-.1% | 89-83-8 | 201-944-8 | Thymol | C N; R20/21/22 R34 R51/53 | ATO 4 EDI 2 EH A2 EH C2; H302 H314 H318 H401 H411 | 980 | 243 | Not determined | Not determined |
(type anisic, medium strength described as sweet, sassafrass, anise, spice, green, herbal, minty, weedy, celery) | ||||||||
0-0.01% | 75-50-3 | 200-875-0 | Trimethyl Amine | F+ Xn C Xi; R12 R20/22 R34 R36/37/38 R41 | FG 1 FL 1 ATO 4 SCI 1B SS 2 EDI 1 EDI 2 ATI 4 STOT SE3; H220 H224 H280 H302 H314 H315 H318 H319 H332 H335 | 500 | 800 | Not determined | Not determined |
(type fishy, very high strength described as fishy, oily, rancid, sweaty, fruity) | ||||||||
0.01% | 110-86-1 | 203-809-9 | Pyridine | F Xn Xi; R11 R20/21/22 R36/38 | FL 2 ATO 4 ATD 4 SCI 2 EDI 2 ATI 4; H225 H302 H312 H315 H319 H320 H332 | 891 | 866 | 28500 | Not determined |
(type fishy, very high strength described as sickening, sour, putrid, fishy, amine) | ||||||||
0-2% | 120-72-9 | 204-420-7 | Indole | : Xn N; R21/22 R37/38 R41 R50/53 | ATO 4 ATD 4 SCI 2 EDI 1 STOT SE3 EH A1 EH C1; H302 H312 H315 H318 H335 H400 H410 | 1000 | 790 | Not determined | Not determined |
(type animal, high strength described as animal, fecal, floral, moth ball, naphthelene, pungent, musty) | ||||||||
0-1% | 111-27-3 | 203-852-3 | 1-Hexanol (Hexan-1-ol) | Xi; R22 | FL 2 FL 3 ATO 4 ATD 4 EDI 1 EDI 2 EH A1 EH C1; H225 H226 H302 H312 H318 H319 H400 H410 | 720 | 3100 | 1060 | Not determined |
(type herbal, medium strength described as ethereal, fusel oil, fruity, alcoholic, sweet, green, pungent) | ||||||||
0-8% | 928-96-1 | 213-192-8 | cis-3-Hex-3-en-1-ol | Xi; R10 R36 | FL 3 EDI 2; H226 H319 | 4700 | 5000 | Not determined | Not determined |
(type green, high strength described as fresh, green, cut grass, foliage, vegetable, herbal, oily, melon rind-like) | ||||||||
0-8% | 89-78-1 | 201-939-0 | Dextro, Laevo(DL)-Menthol | Xi; R37/38 R41 | SCI 2 EDI 1 EDI 2 STOT SE3; H315 H318 H319 H335 | 3180 | Not determined | Not determined | Not determined |
(type mentholic, medium strength described as peppermint, cool, woody) | ||||||||
0-1% | 75-07-0 | 200-836-8 | Acetaldehyde | F+ Xi; R12 R36/37 R40 | FL 1 EDI 2 STOT SE3 CAR 2; H224 H319 H335 H351 | 661 | 640 | Not determined | Not determined |
(type ethereal, high strength described as pungent, ethereal, aldehydic, fruity, fresh, green) | ||||||||
0-.5% | 6789-80-6 | 229-854-4 | cis-3-Hexenal (cisHex-3-enal) | Xi; R10 R22 | FL 3; H226 | 1560 | 3700 | Not determined | Not determined |
(type green, high strength described as green, fatty, grassy, weedy, fruity, apple) | ||||||||
0-.01% | 98-01-1 | 202-627-7 | Furfural (2-Furaldehyde) | Xn T Xi C; R21 R23/25 R36/37/38 R40 | FL 3 ATO 3 ATD 3 SCI 2 EDI 2 ATI 2 STOT SE3 CAR 2 EH C3; H226 H301 H312 H315 H319 H330 H335 H351 H412 | 65 | 148 | 175 | Not determined |
(type bready, medium strength described as sweet, woody, almond, fragrant baked bread, brown, caramelic, nutty, burnt) | ||||||||
0-30% | 6413-10-1 | 229-114-0 | Fructone (Apple Ketal) Methyl Dioxolan | None | None | 5000 | 5000 | Not determined | Not determined |
(type fruity, medium strength described as sweet, fruity, apple, green, tropical, plum, woody) | ||||||||
0-5% | 142-92-7 | Hexyl acetate | Xi; R10 R36/38 | 41500 | 5000 | Not determined | Not determined | |
0-15% | 77-83-8 | Ethyl Methylphenylglycidate | Xi N; R36 R52/53 | 5000 | Not determined | Not determined | Not determined | |
0-5% | 1128-08-1 | Dihydrojasmone | None | 2500 | 5000 | Not determined | Not determined | |
0-.5% | 4312-99-6 | Oct-1-en-3-one | Xi; R10 R22 R36/38 | 175 | 3300 | Not determined | Not determined | |
0-10% | 85213-22-5 | 2-Acetyl-1-Pyrroline | None | Not determined | Not determined | Not determined | Not determined | |
0-1% | 27300-27-2 | 2-Acetyl-3,4,5,6-Tetrahydropyridine | None | Not determined | Not determined | Not determined | Not determined | |
0-1% | 25343-57-1 | 6-Acetyl-2,3,4,5-tetrahydropyridine | None | Not determined | Not determined | Not determined | Not determined | |
0-12% | 107797-26-2 | gamma-Decalactone | Xi; R36/38 | 5000 | 5000 | Not determined | Not determined | |
0-15% | 63357-97-1 | gamma-Nonalactone | None | Not determined | Not determined | Not determined | Not determined | |
0-12% | 698-76-0 | delta-Octalactone | Xi; R36/38 | 5000 | 5000 | Not determined | Not determined | |
0-3% | 34686-71-0 | Jasmine Lactone | Xi; R36/38 | Not determined | Not determined | Not determined | Not determined | |
0-0.01% | 51154-96-2 | Massoia Lactone | Xi | 1890 | Not determined | Not determined | Not determined | |
0-.5% | 182699-77-0 | Wine Lactone | Xi; R36/38 | Not determined | Not determined | Not determined | Not determined | |
0-.5% | 698-10-2 | Maple Furanone | Xi; R22 R36/37/38 | Not determined | Not determined | Not determined | Not determined | |
0-.5% | 28664-35-9 | Caramel Furanone | Xi; R20/22 R36/37 | Not determined | Not determined | Not determined | Not determined | |
0-.1% | 75-08-1 | Ethanethiol, Ethyl Mercaptan | Xn; R12 R20 R50/53 | 682 | Not determined | Not determined | Not determined | |
0-.1% | 71159-90-5 | Grapefruit Mercaptan | Xi; R36/38 | 6000 | Not determined | Not determined | Not determined | |
0-.5% | 74-93-1 | Methanethiol | T N; R12 R23 R50/53 | Not determined | Not determined | Not determined | Not determined | |
0-.1% | 75-66-1 | Tert-butyl Mercaptan | Xi; R12 R36/37 R41 | 8400 | Not determined | Not determined | Not determined | |
0-2% | 2173-57-1 | Nerolin | Xi; R36/38 | 5000 | 5000 | Not determined | Not determined | |
0-1% | 110-01-0 | Tetrahydrothiophene | Xn N; R11 R20/21/22 R36/38 R52/53 | 1200 | Not determined | Not determined | Not determined | |
0-0.01% | 87-40-1 | 2,4,6-Trichloroanisole | Xi | 1890 | Not determined | Not determined | Not determined |
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
IMPORTANT
While the descriptions, data and information contained herein are presented in good fath and believed to be accurate, it is provided for your guidance only. Because many factors may affect processing or application/use, we recommend that you perform assessment to determine the suitability of the product for your particular purpose prior to use. Nothing herein should be interpreted as a recommendation to infringe existing trademarks or patents or violate any laws or regulations. No warranties of any kind, either expressed or implied, including fitness for a particular purpose are made regarding the product described. We assume NO responsibility for any injuries resuilting from misuse or misapplication of this product or that might be sustained because of inhalation, ingestion, absorption or other contact with this product. In no case shall the descriptions, information, or data provded be considered a part of our terms and conditions of sale. Further, the descriptions, data and information furnished hereunder are given gratis. No obligation or liability for the description, data and information given are assumed. All such being given and accepted at your risk.
The information on this safety data sheet complies with Annex II of EU REACH Regulation EC 1907/2006, EU REACH Regulation EC 1272/2008Product Code - Trade Name | Key Note: Pink Peppercorn - INCI: Fragrance |
Specific Gravity at 25°C: | 1.0014 |
Refractive Index at 25°C: | 1.4379 |
Flash Point: | SOS: 230°F ULTRA: 198°F EXTREME: 167. If not listed, please call for flashpoint(s). |
Batch/Test Date: 2019-01-1 #2027592019011
|
ALL REGULATION LIMITS I. PRODUCT INFORMATION
II. APPLICATION
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For all other applications, or use at higher concentration levels, a new evaluation will be required.
The IFRA standards regarding use restrictions are based on safety assessments by the Research Institute for Fragrace Materials (RIFM) Expert Panel (REXPAN), and are enforced by the IFRA Scientific Committee. Evaluation of individual fragrance materials is made according to the safety standards contained in the relevent section of the IFRA Code of Practice. It is the ultimate responsibility of the customer to ensure the safety of the final product containing this fragrance, by further testing if necessary (strongly suggested). The above mentioned fragrance products contains ingredients which are NOT considered GRAS, Generally Regarded as Safe as a Flavor Ingredient. |